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Organic Lab Reactions 36 - 6-Allyl-2-bromo 2-Allyl-4-bromo...

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2,3,5-Trimethyl 4-(0-Carbomethoxyvinyl) 2-Chloro 4-Chloro 2,4-Dichloro 2-Bromo 4-Bromo 2,4-Dibromo * 3,5-Dibromo 2-Nitro 4-Nitro 3-Acetamino 4-Amino 4-Acetamino 2,3,5-Trimethyl-4-formamino 2,3,5-Trimethyl-4-acetamino 2-Allyl-4-acetamino 4-Phenylazo 1 2 0.15 0.4 "Long" 1.8 Few minutes at reflux 2 1.6 5 1.5 6 6 2 7 5 0.5-1 270 230-245 220-224 Reflux (to 256°) 200-210 210-220 213-220 210-220 180 230 185 180 225 225 230 (Inert atmosphere) Tetralin Paraffin oil Refluxed in dimethylaniline (inert atmosphere) Paraffin oil (inert atmosphere) Dimethylaniline (inert atmosphere) Kerosene Kerosene Dimethylaniline (inert atmosphere) Paraffin oil '6-Allyl-2,3,5-trimethyl . 2-Allyl-4-03-cftrbomethoxyvinyl) 6-Allyl-2-chloro 2-Allyl-4-chloro 6-AUyl-2,4-dichloro
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Unformatted text preview: 6-Allyl-2-bromo 2-Allyl-4-bromo 6-Allyl-2,4-dibromo (phenolic by-product) 2-AUyl-3,5-dibromo 6-Allyl-2-nitro 2-Allyl-4-nitro 6-AUyl-3-acetamino 2-Allyl-4-amino 2-Allyl-4-acetamino 6-Allyl-2,3,5-trimethyl-4-formamino 6-Allyl-2,3,5-trimethyl-4-acetamino 2,6-Diallyl-4-acetamino 2-Allyl-4-phenylazo 55% ' 82% >85% >85% — 82% >85% 69% 11% 72% 72% 30-40% >85% 70% >85% >85% >85% — 70% 95,106 80 46 44 (p. 37) 26,45,107 47 44 (p. 38) 47 47 44 (p. 59) 44 (p. 40) 107a 11 (p. Ill) 11 (P-107); 100 95 95 11 (p. 112) 44 (p. 42) * References 104-129 appear on p. 48. t A mixture of the two lsomere was used. CO...
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