Organic Lab Reactions 54

Organic Lab Reactions 54 - 62 Benzotrifluoride 62...

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CHAPTER 2 THE PREPARATION OF ALIPHATIC FLUORINE COMPOUNDS ALBERT L. HENNE Ohio State University CONTENTS PAGE INTRODUCTION 50 METHODS OP PREPARATION 51 Interaction of Organic Halides or Polyhalides with Inorganic Fluorides .. . 51 The Use of Potassium Fluoride, Zinc Fluoride, Antimony Fluorides, and Hydrogen Fluoride -. 51 Table I. Preparation of Aliphatic Fluorides by the Use of Antimony Fluorides 54 The Use of the Fluorides of Silver and Mercury 56 Table II. Preparation of Aliphatic Fluorides by the Use of Mercuric Oxide and Hydrogen Fluoride . .\ 58 Construction of Apparatus and Preparation of Reagents 59 Equipment 59 Reagents , 60 Preparation of Mercurous Fluoride 60 Preparation of Antimony Trifluorodichloride 61 Experimental Procedures 61 Acetyl Fluoride 61 v l,l,2-Trichloro-3,3,3-trifluoro-l-propene
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Unformatted text preview: 62 Benzotrifluoride 62 Laboratory Procedure 62 Industrial Procedure *• • • 62 2,2-Difluoropropane 63 l,l,2,2,3,3-Hexachloro-3-fluoropropane 63 l,l,2,2,3-Penta<Moro-3,3-difluoropropane 63 l,l,l,2,2,3,3-Heptachloro-3-fluoropropane 63 l I l,2,2,3,3-Hexaohloro-l,3-difluoropropane 64 l,l,2,2,3-Pentachloro-2,3,3-trifluoropropane 64 Dichlorodifluoromethane and Trichlorofluoromethane „ 64 l,2-Dichloro-l,l,2,2-tetrafluoroethane 65 l,l-Difluoro-2,2-dibromoethane and l-Fluoro-l,2,2-tribromoethane . . 65 • 1,2-Dibromofluoroethane and l-Bromo-2,2-difluoroethane . . . . . . . 66 Mercury Recovery - 66 Addition of Hydrogen Fluoride to Unsaturated Compounds 66 Addition to a Triple Bond 66 Addition to a Double Bond 67 49...
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This note was uploaded on 11/20/2011 for the course CHM 2210 taught by Professor Reynolds during the Fall '01 term at University of Florida.

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