Organic Lab Reactions 59

Organic Lab Reactions 59 - CHCI2CCI2F (85%) CHCI2CCIF2...

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64 ALIPHATIC FLUORINE COMPOUNDS of the particular product. The yields from bromides, and particularly from iodides, were much lower, owing to concurrent decomposition reac- tions. TABLE I PREPARATION OF ALIPHATIC FLUORIDES BY THE USE OF ANTIMONY FLUORIDES Starting Material CC1 4 CHClj CH 2 C1 2 CHjCl CClgCClj CHCI2CCI3 CHCI2CHCI2 CH2CICCI3 CH2CICHCI2 CH 3 CC1 3 CH2CICH2CI CE3CH2CI CC1 3 CC1 2 CC1 3 Products CCI3F (quant.) CCI2F2 (quant.) CHC1 2 F (quant.) CHCIF2 (quant.) CH2CIF (80%) CHzFj (80%) No reaction CCI3CCI2F (quant.) CCI2FCCI2F (quant.) CCIF2CCI2F (quant.) CCIF2CCIF2 (quant.)
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Unformatted text preview: CHCI2CCI2F (85%) CHCI2CCIF2 (70%) CHCI2CHCIF (60%) CHCI2CHF2 (60%) CH2CICCI2F (80%) CH2C1CC1F 2 (80%) CH2CICHCIF (60%) CH2CICHF2 (30%) CH3CCI2F (90%) CH 3 CC1F 2 (90%) CH 3 CF 3 (90%) No reaction No reaction CCl 2 FCCl2CCl 3 (quant.) CCI2FCCI2CCI2F (quant.) CCl!!FCCl 2 CClF 2 (quant.) Note to to 1,2 1,~2 2 2 ' 3 3 1,2 1,2 1,2 1,2 1,2 1,2 . 1,2 1,2 2 2 to to to Reference 23,24 23,24 25,26 25,26 26 26 27 27 27 27 28 28 12 12 29 29 21 21 21 21 21 5a 5a 30 30 30...
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This note was uploaded on 11/20/2011 for the course CHM 2210 taught by Professor Reynolds during the Fall '01 term at University of Florida.

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