Organic Lab Reactions 60

Organic Lab Reactions 60 - SbF,Cl 2 . 4. The remainder of...

Info iconThis preview shows page 1. Sign up to view the full content.

View Full Document Right Arrow Icon
THE USE OF INORGANIC FLUORIDES 55 TABLE I—Continued PREPARATION OP ALIPHATIC FLUOKIDBS BY THE USE OF ANTIMONY FLUORIDES Starting Material CHC1 2 CC1 2 CC1S CClsCHClCCls CH 8 CH 2 CCla CH 8 CC1 2 CH 8 CH 3 CF 2 COl3 CC1 8 CH 2 CF 8 ccuca^ Products CHC1 2 CC1 2 CC1 2 F (quant.) CHC1 2 CC1 2 CCIF 2 (quant.) CHC1 2 CC1FCC1F 2 (75%) CHC1FCC1FCC1F 2 (20%) CC1JCHC1CC1 2 F (75%) CC1 2 FCHC1CCI 2 F (75%) CClFsjCHClCClaF (30%) CC1F 2 CHC1CC1F 2 (30%) CH 8 CHsCCl 2 F (40%) CH 8 CH 2 CC1F 2 (40%) GH 8 CH 2 CF 3 (40%) CH 8 CC1FCH 3 (quant.) CH 8 CF 2 CH 3 (quant.) CH 3 CF 2 CC1 2 F (60%) ' CH3CF2CCIF2 (10%) CC1 2 FCH 8 CF 8 (quant.) CC1F 2 CH 2 CF S (quant.) CCl 2 FCCl2CF 8 (quant.) CC1F 2 CC1 2 CF 8 (quant.) Note 2 2 1,2 1,2 1,2 1,2 1,2 1,2 2,4 2,4 2,4 to to 1,2 1,2 IN IN 2 2,3 Reference CO CO CQ CO 30 30 31 31 5a 5a 5a 19 19 19,33 5a, 33 5a 5a 5a 5a 1. The remainder of the material underwent chlorination. 2. For the preparation of this product, antimony tnfluoride containing 10% of SbFjCIa was used. 3. For the preparation of this product, the antimony trifiuoride must be converted completely to
Background image of page 1
This is the end of the preview. Sign up to access the rest of the document.

Unformatted text preview: SbF,Cl 2 . 4. The remainder of the material underwent loss of hydrogen chloride. • " Swarts, M4m. couronnis acad. roy. Belg., 61 (1895). •* Midgley and Henne, Ind)Eng. Chem., 22, 542 (1930). 86 Swarts, Bull. acad. roy. Bdg., [3] 24, 474 (1892). 26 Henne, J. Am. Chem. Soc., 59, 1400 (1937). 1 87 Locke* Brode, and Henne, J. Am. Chem. Soc., 56, 1726 (1934). 28 Henne and Ladd, J. Am. Chem. Soc., 58, 402 (1936). *• Henne and Hubbard, J. Am. Chem. Soc., 58, 404 (1936). »° Henne and Ladd, J. Am. Chem. Soc., 60, 2491 (1938). » Henne and Renoll, J. Am. Chem. Soc., 61, 2489 (1939). 82 Henne and Haeokl, J. Am. Chem. Soc., 63, 3476 (1941). 8S MoBee, Henne, Hass, and Elmore, /. Am. Chem. Soc., 62, 3340 (1940)....
View Full Document

This note was uploaded on 11/20/2011 for the course CHM 2210 taught by Professor Reynolds during the Fall '01 term at University of Florida.

Ask a homework question - tutors are online