Organic Lab Reactions 76

Organic Lab Reactions 76 - 68, 69, 70, 71 57, 59, 61 60 63...

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DIRECT FLUORINATION AND ADDITION OF FLUORINE 71 TABLE III PRODUCTS OBTAINED BY DIRECT ADDITION AND SUBSTITUTION OF FLUORINE Starting Material C CH 4 C 8 H 6 CH 8 COCH 8 CHCI3 C2HCI5 CHC1 2 CHC1 2 CCl2=CCl 2 CHCl=CC! a C,C1« n-CieH34 CHsCH=CHCO 2 H Products CF 4 , CzF 4 , C 2 F«, CsF 8 CF 4 , C 2 F 4 , C 2 F 6 , C 3 F 8 CF 4 , C 2 F 6 , CH 2 FCH 2 F, CH 2 FCHF 2 , CHF 2 CHF 2 , ' CHF 2 CF S CF 4) CF 8 C1, CF 2 C1 2 , CF 3 CF 2 C1, CHF 2 CH 2 C1 CF 3 COCFs, CH 2 FCOCH 3 , CH 3 COF, FOCCOF, COF 2) CF 4 CC1 3 F, C 2 C1« CFC1 2 CFC1 2> C 2 C1 4 , C 2 HFC1 4 , C 2 C1 6 , C 4 C1 1O CHC1==CC1 2 , CFC1 2 CFC1 2 , CHa 2 CFCl 2 , CHC1 2 CC1 8 CFC1 2 CFC1 2 , CFC1 2 CC1 3 , C 4 F 2 C1 8 CHFC1CFC1 2 , CFC1=CC1 S , CHFC1CC1 3 , CHC1 2 CFC1 2 , C 4 H 2 C1 6 , C 4 H 2 C1 8 C 6 C1 6 F 6 CH 2 FCHF(CH 2 )i 3 CH 3 CH 3 CHFCHFCO 2 H Note 1,2 1,2 1 1,2 3 Reference 68, 69, 70, 71
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Unformatted text preview: 68, 69, 70, 71 57, 59, 61 60 63 67 67 67 67 67 55, 56, 58 66 66 1. CF4 is the major product. 2. Higher members of the series are also produced. 3. The product is a mixture of twodiastereoisomeric pairs. 68 Moissan, Ccrmpt. rend., 110, 276 (1890). 69 Lebeau and Damiens, Compt. rend., 168, 1340 (1926). 70 Ruff a n dKeim, Z. anorg. allgem. Chew,., 192, 249 (1930). 71 Simons and Block, / . Am. Chem. Soc., 69, 1407 (1937); 61, 2964 (1939)....
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This note was uploaded on 11/20/2011 for the course CHM 2210 taught by Professor Reynolds during the Fall '01 term at University of Florida.

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