Organic Lab Reactions 83

Organic Lab Reactions 83 - n 25 l.35572 M.p. 14.2°, b.p....

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TABLE IV— Continued ALIPHATIC FLUORINE COMPOUNDS oo Formula C2F 2 Br2O C2F 2 Br4 C2F2CI1! C2F2CI2O QjFjiCLi C2FsBr C 2 F3Br2Cl CjFsBrj C2F3CI C2F3CI3 C2F3N C2F4 Structure CFBr 2 COF CBr 2 FCBr 2 F CBr 3 CBrF 2 CC1F=CC1F, trans CC1F=CC1F, eis CF2=CC1 2 CFC1 2 COF CF2CICOCI CFC1 2 CFC1 2 CF2CICCI5' CF2==CFBr CClFBrCF 2 Br CFBr 2 CBrF 2 CC1F=CF 2 CC1 2 FCC1F 2 CF3CCI3 CF 3 CN CF 2 =CF 2 Physical Properties B.p. 75.5° M.p. 62.5°, b.p. 186.5° M.p. 99°, b.p. 485° M.p. -110.3°, b.p. 22.0°, d°1.4936, n°1.3798 M.p. -130.5°, b.p. 21.1°, d°1.4950, n°1.3777 M.p. -115°, b.p. 18.9° B.p. 31° B p. 34° M.p. 24.65°, b.p. 92.8°, d 2B 1.6447, « 26 1.4130 M.p. 40.6°, b.p. 91° B.p. -2.5°, d 18 1.89 B.p. 92.9°, d*>2.2Zl8, « 20 1.4272 B.p. 117°, <f2.5666, n 7 1.4666 M.p. -157.9°, b.p. -27° M.p. -36.4°, b.p. 47.7°, ^1.5635,
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Unformatted text preview: n 25 l.35572 M.p. 14.2°, b.p. 45.9°, dP\.81W>, B.p. -61° M.p. -144°, b.p. -78.4° Preparation (yield, remarks) CBr 8 COCl + SbF 3 + Br 2 at 130° CFBr=CFBr + Br 2 CBr2=CF2 + Br 2 CCI2FCCI2F + Zn V^V^IQJ? V - / \ ^ X 5 ^ " I"" #^T1 CC1 3 CF 2 C1 + Zn (CC1 3 CO)2O + SbF 3 + Br 2 at 95° CHF2CH2OH + Cl 2 in sunhght C 2 C1 6 + SbF 3 + SbCl 6-CHCI2CHF2 + Cl 2 CFBr 2 CF 2 Br + Zn CC1F=CF 2 + Br 2 CFBr=CF 2 + Br 2 CF2CICFCI2 + Zn C 2 C1« + SbF 3 Cl 2 CH 3 CF 3 + Cl 2 CF 3 CONH 2 + P ^ CF4CICF2CI + Zn Refer-ence * 117 117 94 27 • 27 116 23 23 27 116 118 27 118 27 27 116 85 27...
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This note was uploaded on 11/20/2011 for the course CHM 2210 taught by Professor Reynolds during the Fall '01 term at University of Florida.

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