Organic Lab Reactions 85

Organic Lab Reactions 85 - 1.496, n 20 1.327 M.p. -15.5,...

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TABLE IV— Continued ALIPHATIC FLUORINE COMPOUNDS Formula C 2 HF 2 Br C2HF2B1O2 • C2HF 2 Br!!Cl C 4 HFaBr 3 C2HF2CI C 2 HF 2 CIO C2HF2CIO2 C2HF2C1 S C2HF2N C2HF3 C2HF 3 Br 2 G2HF3CI C2HF3O2 C2HF4CI C2HFB QjHFeN ^ Structure CHC1 2 CC1 2 F CF2=CHBr ' CHF=CBrF CF 2 BrCO 2 H CHClBrCF 2 Br CFBr 2 CHFBr CHBr 2 CBrF 4 CHC1=CF 2 CHF2COCI CF2C1CO2H CHClsCClFf CHClFCa 2 F CHF2CC33 CHF 2 CN CHF=CF 2 CBrF 2 CHBrF CHC1FCC1F 2 - CF3CO2H CHF 2 CF 2 C1 CF 3 NHCF S Physical Properties M.p. -82.6°, b.p. 116.6°, d 20 1.6223, n 20 1.4487 B.p. 6.2°, d°1.82 B.p. 19.6°, d°1.8337, n°1.3846 M.p. 40°, b.p. 145-160° B.p. 118.7°, n^l^l l B.p. 146°, d 20 2.6028, n 17 1.5078 B.p. 143.5°, <F2.6130, n 17 1.5025 B.p. 2.4° B.p. 25° M.p. 22.9°, b.p. 121.5° B.p. 71.9°, <Z 25 1.54472, n M 1.3889 B.p. 72.5", d 26 1.5492, n*1.3916 B.p. 73.0°, dP\.5m\, n 20 1.3979 B.p. 22.8-23.4° B.p. -51°, «P 8 1.26 B.p. 76.5°, d lo 2.2713, n lo 1.4171 B.p. 28°, d 1()
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Unformatted text preview: 1.496, n 20 1.327 M.p. -15.5, b.p. 72.4 B.p. -12&quot; M.p. -103, b.p. -48.5 M.p. -130 Preparation (yield, remarks) CHCljjCCls + SbF 3 Cl 2 CBrFjCE^Br + CH3CO2K + K2CO3 CHBrFCBr2F + Zn CHF 2 CX) 2 H + Br 2 at 160 CHC1=CF 2 + Br 2 CBrsCHFBr + SbF 3 + Br 2 CF2=CHBr + Br 2 CHa 2 CClF 2 + Zn CHF 2 CO 2 H + PCI5 CHF 2 CO 2 H + Cl 2 C 2 HC1 6 + SbFsCl2 CHClFCa 3 + SbF 3 + Cl 2 CHC1 2 CHF 2 + Cl 2 CHF 2 CONH 2 + P2O6 CF 2 BrCHFBr + Zn CBr 3 CHFBr-+ SbF 3 + Br 2 CHCI 2 GC!IF 2 + SbF 3 Cl 2 ^ Oxidation of triftuorotoluidine By-product of preparation of CHC^CCliF F 2 + C2H By-product of ICN + PF 6 Refer-ence * 28 94 83 84 28 117 94 28 84 81 28 28 28 120 118 117, 118 28 85 28 61 119...
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This note was uploaded on 11/20/2011 for the course CHM 2210 taught by Professor Reynolds during the Fall '01 term at University of Florida.

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