Organic Lab Reactions 87

Organic Lab Reactions 87 - B.p. 73.9, <P1.3814,...

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TABLE IV— Continued AllPHATIC FlAJORINE COMPOUNDS 00 to Formula C2H2F2O2 C2H 2 F 3 Br C2H 2 F S C1 C2H2F3NO C2H2F4 C2H3F C 2 H 3 FBrCl C 2 H3FBrNO C2H3FBr 2 C2H8FCI2 C2H3FINO C2H3FO Structure CH2CICCIF2 CHF2CO2H CH2FCF 2 Br CF 3 CH 2 Br CHF 2 CHFBr . CHF2CHFCI CF3CH2CI CF3CONH2 CHF2CHF2 CH2=CHF CHClFCH 2 Br CHFBrCONHs CH 2 FCHBr 2 CHFBrCH 2 Br CH3CCI2F CHCIFCH2CI CHIFCONH 2 CH3COF Physical Properties M.p. -101.2°, b.p. 46.8°, (Pl.4163, n M 1.36193 M.p. 35°, b.p. 134.2° B.p. 250° 3-p. 26.5°, d 17 - 6 1.8383 B.p. 41°, d lo 1.874, » 10 1.36175 B.p. 17°, d lo 1.365 B.p. 6.1°, d°1.389, n°1.3090 M.p. 74.8°, b.p. 162.5° B.p. -23° M.p. -160.5°, b.p. -72.2°, M.p. -67.7°, b.p. 96.6°, cFl.8291, n 20 1.4546 M.p. 44° B.p. 117.5°, n 20 1.50084 M.p. -54°, b.p. 122°, d lo 2.26333, n 20 1.51759 B.p. 31.7°, d 6 1.2673, n 6 1.38679
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Unformatted text preview: B.p. 73.9, <P1.3814, n 20 1.41132 M.p. 92.5 B.p. 20.5, d1.0369 Preparation (yield, remarks) CH2CICCI3 + SbF 3 + SbCls CHF 2 CH 2 OH + CrO 3 CBrF 2 CH 2 Br + AgF CF 3 CH 2 OH + PBr 5 CHBrjCHBra + HgF 2 CHCI2CHCI2 + SbF 3 + SbCls CHC1 2 CHC1 2 + SbF s Cl 2 Ester + NH4OH (48%) CHBr 2 CHF 2 + HgF 2 C 2 H 2 +'HF CHClBrCH2Br + SbF 3 + Br 2 Ester + 20% NH4OH By-product from CH 2 BrCHBr2 + SbF 3 + CHBr 2 CH 2 Br + SbF 3 + Br 2 or HgF 2 CH3CCI3 + SbF 3 + SbF 3 Cl 2 CH 2 C1CHC1 2 + HgF 2 Ester + NH 3 CHsCOCl + ZnF 2 or (CH 3 CO) 2 O + HF Refer-ence * 29 122 94 123 36 82 36 85 36 124 36 82 125 39,125 21 21 82 2,43...
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