Organic Lab Reactions 89

Organic Lab Reactions 89 - n 20 1.4002 M.p. 41, b.p. 112.5...

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TABLE IV— Continued ALIPHATIC FLUORINE COMPOUNDS Formula CW3U C 3 F 3 CU C 3 F4Br 2 Cl 2 CgF4Cl2 C3F4C14 C 3 F 6 O CsFg QHFCU Structure CCI3CCI2CCIF2 CCI2FCCI2CCI2F CC1 3 CF2CC1 3 CCI3CF2CCI2F CCI3CCIFCCIF2 CCI2FCCI2CCIF2 CClFBrCFBrCClF 2 CC1F==CFCC1F 2 CClsCFiiCF^l CCl^CClFCClFi! CC1F 2 CC1 2 CC1F 2 CC1 3 CC1FCF» CC1 2 FCC1 2 CF 3 CF3COCF3 ccisCHacazF Physical Properties M.p. 51°, b.p. 193.4° M.p. 298°, b.p. 194.2° M.p. -12.9°, b.p. 194.4°, d^LSlO^ n m l .47996 B.p. 154.5°, (Fl^gO, n w 1.4S94 M.p. -15°, b.p. 153.4°, d 20 1.7702, « 20 1.4392 M.p. -4.9°, b.p. 152.3°, d 20 1.7702, M.p. 35.5-37°, b.p. 154° B.p. 43.5°, d lo 1.555 B.p. 112.3°, d 20 1.6992, n^l^e i M.p. -58°, b.p. 112.5°, d^UlSS, n 20 1.3960 M.p. -42.9°, b.p. 112.0°, d 20 !.?! 0 ^, n 20 1.3958 M.p. 12°, b.p. 112.5°, d 20 1.7254,
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Unformatted text preview: n 20 1.4002 M.p. 41, b.p. 112.5 M.p. -129, b.p.-28' M.p. -183, b.p. -36 B.p. 207, d 20 1.76188, JI 20 1.50105 Preparation, (yield, remarks) CHC1 2 CC1 2 CC1F 2 + Cl 2 C3CI8 + SbF 3 + SbF 3 Cl 2 CH 3 CF 2 CH 3 + Cl 2 CCl 3 CF 2 Ca 3 + SbF 3 Cl 2 CHC1 2 CC1FCC1F 2 + Cl 2 C3CI8 + SbF 3 Cl 2 Br 2 + CC1F=CFCC1F 2 CC1 2 FCC1FCC1F 2 + Zn CI 2 + CH 2 C1CF 2 CF 2 C1 l-'Ul^Ov-'lr OOlr 2 ~r ODX 3UI2 C 3 C1 8 + SbF 3 Cl 2 CCl2=CFCF 3 + Cl 2 CC1 3 CC1 2 CF 3 + SbFsCl 2 CH3COCH3 + F 2 C 2 H 8 + F 2 ; C + F 2 CCUCHClCCls + SbF 3 + SbCIle Refer-ence * 30 30 20,33 19,30 31 * 30,31 5a 5a 33 5a 31 5a 5a 63 62, 71, 101 30...
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