Organic Lab Reactions 91

Organic Lab Reactions 91 - M.p. -84.5, b.p. 4 M.p. 55-56...

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TABLE IV— Continued ALIPHATIC FMJOBINE COMPOUNDS Formula CaHsFO CsH6FO 2 C3H5F 2 Br C3HBF2CI C3H6F3O CsHeFCl C3H 6 F 2 CsHeF/) C3H7F C 4 F 2 C1 8 C 4 F 6 O 3 C4F 10 C 4 H2F2C1 6 C4H2F 6 O2 \ Structure CH2FCOCH3 CH2FCO2CH3 FCO 2 C2H B CH 3 CF 2 CH 2 Br CH 3 CF 2 CH 2 C1 CH 2 FCF 2 OCH 3 CF3CHOHCH3 CH3CFCICH3 CH3CH2CHF2 CH 3 CF2CH 3 CHF2CH2OCH3 CH 3 CH 2 CH 2 F CHsCHFCH 3 CCI2FCCI2CCI2CCI2F CC1 3 CF 2 C2C1 5 (CF 3 CO) 2 O CF3CO2CH2CF3 Physical Properties B.p. 72° or 78° B.p. 104°, d 15 1.1613 B.p. 57° B.p. 76.2°, ePl.6102 or 1.38860 B.p. 55.1°, d 20 1.2023, n w 1.3506 B.p. 45° B.p. 77.4°, d 16 1.2799, n 16 1.31720 B.p. 35.2°, d lo l.OO72, n lo l.35856 B.p. 7-8° B.p. -0.5°, oPO.9205, n" 42 6 1.3118 B.p. 47° M.p. -150°, b.p. -32° M.p. -133°, b.p. -94° M.p. 4°, b.p. 152720 mm., d 20 1.9272, n^l^ e M.p. -2°, b.p. 10872 mm., d 20 1.8994, n M 1.5139
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Unformatted text preview: M.p. -84.5, b.p. 4 M.p. 55-56 M.p. -65.5, b.p. 55, d 18 1.4725, n 18 l 2812 Preparation (yield, remarks) CH2ICOCH3 + T1F; CH 2 BrCOCH 3 + T1F; CH3COCH3 + F 2 y CH 2 ICO 2 CHs + AgF or T1F C1CO 2 C 2 H 6 + T1F SbF 3 + CH 3 CClBrCH 2 Br Cl 2 + CHaCFjCHj CH2FCF 2 Br + NaOCH 3 CF 3 COCH 3 + H 2 CH3CCI2CH3 + SbF 3 CH3CH2CHCI2 + HgF 2 CH 3 CC1 2 CH 3 + SbF 3 CHF 2 CH 2 Br + KOH + CHgOH CsHjI + AgF CH2=CHC53 + HF C 2 C1 4 + F 2-CH 3 CF 2 C 2 H 6 + Cl 2 CF 3 CO 2 H + P2O5 C + F 2 CHa=CCl 2 + F 2 (CF 3 CO) 2 O + H 2 + Pt Refer-ence * 95, 111 95, 113 95 19 19,33 94 90 19 20 19 94 129 46 67 20 88 71 67 88...
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