Organic Lab Reactions 93

Organic Lab Reactions 93 - 12 0.7527, n 12 1.3241 M.p....

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TABLE IV— Continued ALIPHATIC FLUOBUJE COMPOUNDS Formula C 4 HrFOj C4H 7 FjBr0 C^FsNjOi! C 4 H T F,0 C4H7F4N C4H8FI CiHgF-s C 4 HgF2O C4H9F C5F2CI10 CsFia C 6 H 7 F 2 CUHJFJOJ CBHrFsNijOs Structure CH3(CH 2 F)CHCO 2 H CH2FCO2C2H S CH 2 BrCF 2 OC2H5 CF,C(ONHt)=CHCO- NH 2 CF3C(CH 8 )2OH (CHF 2 CH 2 )2NH CH3CF2C2H5 C2H6OCH2CHF2 C5H7CH2F CH3CHFC2H6 (CH 3 )2CHCH2F (CH 8 ) 3 CF CCI3CF2C3CI7 CH 3 (CF 3 )CHOCOCH3 Allophanate of CF3CHOHCH3 Physical Properties B.p. 80-82°/13 mm. B.p. 120° or 126°, d 2O l.O926, n 20 ! .37665 B.p. 114^115° M.p. 97° M.p. 20.75°, b.p. 81 6°, d^l.lQOS B.p. 124.4°, d 16 1.30412 B.p. 50°, dl.74, n 16 1.49 B.p. 30.8°, <2 10 0.9164, n lo 1.31862 B.p. 66.5°, d 1B l.O39 B.p. 32°, d 16 0.7824, n 15 1.3419 B.p. 25.2°, d°0.7884, n 12 1.3366 Liquid at +16° M.p. -77° , b.p. 12.1°, d
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Unformatted text preview: 12 0.7527, n 12 1.3241 M.p. 10-15 M.p. - 1 0 , b.p.30 M.p. 52 B.p. 85.6/75 mm., <* 16 1.1823, n1.3314 M.p. 160 Preparation (yield, remarks) Isobutyric acid + F2 CH2CICOC2H5 + KF. BrCH2CO2C 2 H 6 + T1F CBrF 2 CH2Br + NaOC 2 H 5 NH 3 + CFSCOC^COJCJHB CF3CO2R + 2CHsMgI CHF 2 CH2Br + NH S CH3CBrICH 2 CH 3 + HF CH3CCI2C2HS + SbF, CHF 2 CH 2 Br + KOC2H5 C 4 H 9 I + HgF HF + butene \ (CH 3 ) 2 CHCH 2 I + AgF HF + isobutytene CHSCF2C3H7 + Cl 2 C + F 2 CH3CF 2 CH7 + Cl 2 CF3CHOHCH3 + CHjCOCl \ Refer-ence * 66 82, 133 94 86 92 96 134 20 135 136 47 137 47 20 71 20 92 92...
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This note was uploaded on 11/20/2011 for the course CHM 2210 taught by Professor Reynolds during the Fall '01 term at University of Florida.

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