Organic Lab Reactions 94

Organic Lab Reactions 94 - 2 + Br 2 C 2 H 6 OCH 2 CHFCH2Br...

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C 6 H 9 FBr 2 0 QjHgFO CeHgFOa C6H9F2NO2 C 5 HioFBrO C5H10F2 C5H10F2O CgHnF CBFM C6H 7 F 3 O 3 C6H 8 F 2 O 3 C 6 H 8 F3NO2 C 6 H 9 F 3 O 2 C 6 H»F 6 O 4 P C 6 HioFC10 4 CtHi 0 F 2 Cl 2 O CaHnFOs C 6 H 12 F2 C6H12F2 C 2 H 6 OCH2CBrFCH 2 Br CH2=CFCH2OC2H 6 CH3CHFCO2C2H5 CHF 2 CH 2 NHCO2C2H 6 C 2 H 6 OCH 2 CHFCH 2 Br CH3CF2C3H7 C 2 H 6 OCH 2 CHFCH 2 F CH 3 (CH 2 )4F (CH 3 )2CH(CH 2 )2F CH^HFCSH T CH 2 FC(CH 3 )C2H 6 C 2 H 6 C(CH 3 )2F CF 3 COGH2CO 2 C 2 HB CHF 2 COCH 2 CO 2 C 2 H 6 CF 3 C==NHCH 2 CO2- C 2 H 6 CF 3 CO 2 C 4 H 9 (CHF 2 CH 2 ) 3 PO 4 d-Glucosyl fluoride-6- chlorhydrin CHa 2 CF 2 OC4H9-sec d-Glucosyl fluoride CHsCFaCJI, CaHsCFaCsH? B.p. 188° B.p. 77.5°, d 15 0.9166, n 15 1.3790 B.p. 138.41° M.p. 37.6°, b.p. 185° B.p. 157° B.p. 59.8°, ^0.8958, n*°1.3357 B.p. 114.5° M.p. -80°, b.p. 62.8°, dF0.72Sti B.p. 53.5° B.p. .50° B.p. 55.9° M.p. -121°, b.p. 44.8°, d^.lSih, n 44 1.3375 M.p. -4° , or glass, b.p. 51° or 60° M.p. -39°, b.p. 131.5° B.p. 70°/28 mm., b.p. 160°, d 20 1.2418, n w lA059 M.p. 25.2°, b.p. 1577145 mm. B.p. 100.2°, d 22 1.0268, n 22 1.353 B.p. 253-255° ' Dec. 138°, [a]D°88.8 in water B.p. 154°, <?°1.215, n 18 1.4051 M.p. 118-125°, [a]|, 8 96.7° in H 2 O B.p. 86.6°, ^o.sgig, n^issss B.p. 86.8°, (^0.9024, n w l.3553 C 2 H 6 OCHjCF=CH
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Unformatted text preview: 2 + Br 2 C 2 H 6 OCH 2 CHFCH2Br + NaOCH 3 CH 3 CHBrCO 2 C 2 H5 + AgF + CaF 2 Difluoroethylamine + ethylchlorocarbamate C 2 H 6 OCH 2 CHBrCH 2 Br + HgF or AgF CH 3 CC1 2 C 3 H 7 '+ SbF 3 C 2 H 5 OCH 2 CHBrCH2Br + AgF or HgF CsHnBr + HgF tso-CsHuBr + HgF CH 3 CHIC 3 H 7 + AgF Bromide + AgF in acetonitrile (CH 3 ) 2 C=CHCH 3 + HF C+F 2 CF 3 CO 2 C 2 H 6 + CH 3 CO 2 C 2 HB + NaOCjHs CHF 2 CO 2 H + CH 3 CO 2 C2H 6 + NaOC 2 H 6 CF 3 C(ONH 4 )=CHCO2C2H B at 100 CF 3 COC1 + NaOC 4 H 9 CHF2CH2O1H + P + Br 2 Na in CHsOH + aceto-l-fluoro-d-glucose-6-chlorhydrin CHa2CF 2 Cl + KOH + sec-butyl alcohol Saponification of acetofluoroglucose by 1% CH 3 ONa in abs. CH 3 0H CH=CC 4 H 9 + HF CH 3 C^CC 3 H 7 + HF 138 138 66 96 138 20 138 139 139 140 141 47 71 . 86 127 86 5a 142 143 126 144, 145 18 18 * References 97-153 appear on pp. 9293....
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