Organic Lab Reactions 95

Organic Lab Reactions 95 - ) 138.02 in CHQs M.p. 151-152,...

Info iconThis preview shows page 1. Sign up to view the full content.

View Full Document Right Arrow Icon
TABLE IV— Continued ALIPHATIC FLUORINE COMPOUNDS Formula CeHiaF , C6H13FO2 C 7 H8F 3 O 4 CyHnFaOa C 7 H 14 F 2 CjHisF CgHuF C 10 H 2 iF C11H15FO7 CuHieFClO? CuHwFOg C12H21FO10 Structure Normal 2-Fluorohexane 2-(or 3)-Fluorohexane 2-(or 3)-Fluorohexane CH2FCH(ocya:6)2 CFjC4H 7 (CO!iH) 2 Triflu- oromethyl adipic acid CF3COOC5H11-WO CHF 2 C 6 Hi3 CH3CF2C5H11 Normal CH 3 (CH 2 )6CHFCH 3 Normal FluorotriacetyW-ara- binose Aceto-1-fluoro-d-glucose- -6-chlorhydrin ^ 2-Fluorotriacetylfruc- " tose cc-Lactosyl fluoride Gentiobiosyl fluoride Physical Properties B.p. 93.5°, (^0.8002, « 20 1.3748 B.p. 69-72° B.p. 86.3°, (FO^ie, n w 1.3693 M.p. -104°, b.p. 82.6°, d°0.819, n 26 1.3683 B.p. 60725 mm. B.p. 119.5°, d 16 1.0834, n 16 1.3530 B.p. 119.7°, d?°0.8959, n 20 1.37098 B.p. 112.4°, d^O.SSSg, n^l^oSS M.p. -73°, b.p. 119.2°, cPHi.SOSQ, » 21 1.3855 B.p. 139.3° B.p. 142.5°, d°0.798 B.p. 183.5°, d 10 0.792 M.p. 117-118°, [«]g
Background image of page 1
This is the end of the preview. Sign up to access the rest of the document.

Unformatted text preview: ) 138.02 in CHQs M.p. 151-152, [a]|, 106.95 in CHCls M.p. 134-135, g-128.8 D S 83.2 in water [a]g"33.47 in water [sinters 180] Preparation (yield, remarks) CeHisBr + HgF Iodide + HgF By-product of preparation of CeHnF 8ec-Hexyl iodide + Ag2SiFe Bromoacetal + T1F By-product of nitration of CeHsCFg CF8CO2H + isoamyl alcohol CHi3CHCl2 + HgF 2 CH^CCsHn + HF Bromide + HgF Iodide + AgF (violent) Iodide + AgF Bromide + AgF Corresponding acetyl derivative + HF HF and f ructosepentaacetate Heptaacetylfluorolactose + Na in CH3OH NH 3 in CH3OH on 6-(tetraacetyl-|8-gluco-sido)-2,3,5-tribenzoyl glucosyl fluoride Refer-ence * 136 140 136 146 147 85 90 20 18 139 139 139 139 148 143 149 150 144...
View Full Document

Ask a homework question - tutors are online