Organic Lab Reactions 159

Organic Lab Reactions 159 -...

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154 THE FORMATION OF CYCLIC KETONES TABLE VII— Continued SOME CTCXIZATIONB BY THE FMEDEL-CRAPTS ALTJMINTFVI CHLORIDE METHOD Acids Submitted to Cyclization Perinaphthane-7-acetic acid 9a, 1,2,3-tetrahydro- ftf-PerinapMhanepropioniC acid 9a, 1,2,3-tetrahydro- PHENANTHKENE DERIVATIVES 6 1 JO 0-1-Pkenanthrylpropimdc acid f)-2-Phenan(hrylpropKmic add 9,10-dihydro- /3-methyl- P, l-dimethyl-7-isopropyl- 0-methyl- (3-9-Phenanthrylpropionic acid y-2-Phenanthrylbutyric acid 9,10-dihydro- •Y^-Phenanthrylbutyric acid a-carboxy-7-methyl-
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Unformatted text preview: l-methyJ-7-isopropyl-y-4^Phenanthrylbufyric acid l,10-dimethylene-S,6,7,8-tetrahydro-ANTHRACENE DERIVATIVES y-2-Anlhryibutyric acid BENZANTHRACENE DERIVATIVES l,2-Benianthracene-5-acelic acid Yields of Ketones 60% 75% (/)() 31% (fc)(07%* (/) 69% (/) 74% * *) 32% * (/)() 95% (/))81%* (/)(fc)(u) 57% (*)() 63%* (fc) 77% * tf)(65% (t) 35% (/) 62% (fc) 72% * (c) 74% * Reference 30 30 42 58 44; cf. 179 42 180; cf. 181 49 42 43 43 97 56 182; cf. 181 90 56 48...
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This note was uploaded on 11/20/2011 for the course CHM 2210 taught by Professor Reynolds during the Fall '01 term at University of Florida.

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