Organic Lab Reactions 339

Organic Lab Reactions 339 - Anisole (72%) Phenetole (75%)...

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TABLE IV ALKALINE FORMALDEHYDE DEAMINATIONS Amitie Aniiinft o-Toluidine p-Toluidine 2,4-Dimethylaniliiie o-Anisidine p-Anisidine o-Ethoxyaniline p-Ethoxyaniline \\— O-/~~V-NHj NH, Product, Yield Benzene (60%) Toluene (80%) Toluene (80%) m-Xylene (80%) Anisole (75%)
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Unformatted text preview: Anisole (72%) Phenetole (75%) Phenetole (65%) Diphenyl ether (60%) Diphenyl ether (60%) Remarks NassSnOj! or H3PO2 also give a 60% yield. < H3PO2 gives 70-75%. H3PO2 gives 77-83%. Reference 4 4 4 4 4 4 4 4 4 4...
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