310_22 - Organic Lecture Series CH 310 N LECTURE 22...

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Organic Lecture Series 1 CH 310 N LECTURE 22 Textbook Assignment: Chapter 24: Diels Alder 24.6 & 24.7 Homework (for credit): Problem Set – 8 Posted Today’s Topics: The Diels-Alder Rxn Notice & Announcements: EXAM 2: Pick up @ office hrs Organic Lecture Series 2 Amines Amines Epinephrine (adrenaline) Chapter 23
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Organic Lecture Series 3 Medicinal Chemistry Cocaine Topical anesthetic (local) CNS stimulant Organic Lecture Series 4 3 2 3 2 3 2 Alkanolamines (Ethanolamines) Procaine Medicinal Chemistry
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Organic Lecture Series 5 Synthesis of Procaine Synthesis of Procaine Medicinal Chemistry Organic Lecture Series 6 Synthesis of Procaine Synthesis of Procaine HN CH 2 CH 3 CH 2 CH 3 O + Medicinal Chemistry
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Organic Lecture Series 7 2 2 2 2 H 2 Ni Procaine (novocaine) Synthesis of Procaine Synthesis of Procaine Medicinal Chemistry Organic Lecture Series 8 Medicinal Chemistry
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Organic Lecture Series 9 Carbon Carbon - - Carbon Carbon Bond Formation Bond Formation and Synthesis and Synthesis Begin with Sec 24.6-Diels Alder Organic Lecture Series 10 Summary of C Summary of C —C Bond Reactions C Bond Reactions ± Gilman & Grignard additions ± Alkyne and - CN anions ± Alkylation of enolates ± Alkylation of enamines Nucleophilic displacement of a leaving group by “R -
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Organic Lecture Series 11 ± Gilman, Grignard & organolithium ± Alkyne and CN anions ± Aldol reactions ± Claisen & Dieckmann ± Enamine acylations ± Wittig & variations Nucleophilic addition To carbonyl & carboxyl groups Organic Lecture Series 12 ± Michael reaction Conjugate addition to α,β - unsaturated carbonyls ± Simmons-Smith ± cyclopropanations Carbene / carbenoid additions ± Friedel Crafts alkylation & acylations ± Diazonium with CN Electrophilic Aromatic Substitutions
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This note was uploaded on 11/21/2011 for the course CH 51455 taught by Professor Colapret during the Spring '11 term at University of Texas at Austin.

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310_22 - Organic Lecture Series CH 310 N LECTURE 22...

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