Eigenfunctions and Eigenvalues

Eigenfunctions and Eigenvalues - the formula (52) What if...

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Eigenfunctions and Eigenvalues An eigenfunction of an operator is a function such that the application of on gives again, t imes a constant. (49) where k is a constant called the eigenvalue . It is easy to show that if is a linear operator with an eigenfunction , then any multiple of is also an eigenfunction of . When a system is in an eigenstate of observable A (i.e., when the wavefunction is an eigenfunction of the operator ) then the expectation value of A is the eigenvalue of the wavefunction. Thus if (50) then (51) assuming that the wavefunction is normalized to 1, as is generally the case. In the event that is not or cannot be normalized (free particle, etc.) then we may use
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Unformatted text preview: the formula (52) What if the wavefunction is a combination of eigenstates? Let us assume that we have a wavefunction which is a linear combination of two eigenstates of with eigenvalues and . (53) where and . Then what is the expectation value of A? (54) assuming that and are orthonormal (shortly we will show that eigenvectors of Hermitian operators are orthogonal). Thus the average value of A is a weighted average of eigenvalues, with the weights being the squares of the coefficients of the eigenvectors in the overall wavefunction....
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This note was uploaded on 11/22/2011 for the course CHEMISTRY CHM1025 taught by Professor Laurachoudry during the Fall '10 term at Broward College.

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Eigenfunctions and Eigenvalues - the formula (52) What if...

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