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Unformatted text preview: will be infinite if we actually have a complete set of one electron functions ). Similarly, we construct the matrix in this basis by . If we solve this matrix equation, , in the space of all possible Slater determinants as just described, then the procedure is called full configuration-interaction , or full CI. A full CI constitues the exact solution to the time-independent Schrdinger equation within the given space of the spin orbitals . If we restrict the -electron basis set in some way, then we will solve Schrdinger's equation approximately . The method is then called ``configuration interaction,'' where we have dropped the prefix ``full.'' For more information on configuration interaction, see the lecture notes by the present author [ 7 ] or one of the available review articles [ 8 , 9 ]....
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This note was uploaded on 11/22/2011 for the course CHEMISTRY CHM1025 taught by Professor Laurachoudry during the Fall '10 term at Broward College.
- Fall '10