Molecules are octahedral and nonpolar when all six substituents are the same

Molecules are octahedral and nonpolar when all six substituents are the same

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Molecules are octahedral and nonpolar when all six substituents are the same. If the six substituents are not the same polar molecules can result, SF 5 Cl is an example. Octahedral electronic arrangement: AB 6 , AB 5 U, and AB 4 U 2 Electronic Structures Octahedral electronic arrangement: AB 6 , AB 5 U, and AB 4 U 2 shape Octahedral electronic arrangement: AB 6 , AB 5 U, and AB 4 U 2 Valence Bond Theory (Hybridization) Octahedral electronic arrangement: AB 6 , AB 5 U, and AB 4 U 2 If lone pairs are incorporated into the octahedral structure, there are two possible new shapes.
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Unformatted text preview: 1. One lone pair - square pyramidal 2. Two lone pairs - square planar The lone pairs occupy axial positions because they are 90 o from four bonding pairs. Results in decreased repulsions compared to lone pairs in equatorial positions. Octahedral electronic arrangement: AB 6 , AB 5 U, and AB 4 U 2 AB 5 U molecules have: 1.1. octahedral electronic arrangement 1.2. Square pyramidal shape 1.3. and are polar . One example of an AB 5 U molecule is IF 5...
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This note was uploaded on 11/25/2011 for the course CHEM 1211 taught by Professor Atwood during the Fall '07 term at University of Georgia Athens.

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