Thermodynamics filled in class notes_Part_106

Thermodynamics filled in class notes_Part_106 - 6.3....

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Unformatted text preview: 6.3. CONCISE REACTION RATE LAW FORMULATIONS 219 pliers. Continue to find N summationdisplay i =1 ln parenleftbigg i RT P o parenrightbigg ij = G o j RT , j = 1 ,...,J, (6.137) exp parenleftBigg N summationdisplay i =1 ln parenleftbigg i RT P o parenrightbigg ij parenrightBigg = exp parenleftbigg G o j RT parenrightbigg , j = 1 ,...,J, (6.138) N productdisplay i =1 parenleftbigg i RT P o parenrightbigg ij = exp parenleftbigg G o j RT parenrightbigg , j = 1 ,...,J, (6.139) parenleftbigg RT P o parenrightbigg P N i =1 ij N productdisplay i =1 i ij = exp parenleftbigg G o j RT parenrightbigg , j = 1 ,...,J, (6.140) N productdisplay i =1 i ij = parenleftbigg P o RT parenrightbigg P N i =1 ij exp parenleftbigg G o j RT parenrightbigg bracehtipupleft bracehtipdownrightbracehtipdownleft bracehtipupright = K c,j , j = 1 ,...,J, (6.141) In summary, N productdisplay i =1 i ij = K c,j , j = 1 ,...,J. (6.142) Thus, extremization of Gibbs free energy is consistent with equilibrating each of the...
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Thermodynamics filled in class notes_Part_106 - 6.3....

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