Thermodynamics filled in class notes_Part_106

# Thermodynamics filled in class notes_Part_106 - 6.3 CONCISE...

This preview shows pages 1–2. Sign up to view the full content.

This preview has intentionally blurred sections. Sign up to view the full version.

View Full Document
This is the end of the preview. Sign up to access the rest of the document.

Unformatted text preview: 6.3. CONCISE REACTION RATE LAW FORMULATIONS 219 pliers. Continue to find N summationdisplay i =1 ln parenleftbigg ρ i RT P o parenrightbigg ν ij = − Δ G o j RT , j = 1 ,...,J, (6.137) exp parenleftBigg N summationdisplay i =1 ln parenleftbigg ρ i RT P o parenrightbigg ν ij parenrightBigg = exp parenleftbigg − Δ G o j RT parenrightbigg , j = 1 ,...,J, (6.138) N productdisplay i =1 parenleftbigg ρ i RT P o parenrightbigg ν ij = exp parenleftbigg − Δ G o j RT parenrightbigg , j = 1 ,...,J, (6.139) parenleftbigg RT P o parenrightbigg P N i =1 ν ij N productdisplay i =1 ρ i ν ij = exp parenleftbigg − Δ G o j RT parenrightbigg , j = 1 ,...,J, (6.140) N productdisplay i =1 ρ i ν ij = parenleftbigg P o RT parenrightbigg P N i =1 ν ij exp parenleftbigg − Δ G o j RT parenrightbigg bracehtipupleft bracehtipdownrightbracehtipdownleft bracehtipupright = K c,j , j = 1 ,...,J, (6.141) In summary, N productdisplay i =1 ρ i ν ij = K c,j , j = 1 ,...,J. (6.142) Thus, extremization of Gibbs free energy is consistent with equilibrating each of the...
View Full Document

## This note was uploaded on 11/26/2011 for the course EGN 3381 taught by Professor Park-sou during the Fall '11 term at FSU.

### Page1 / 2

Thermodynamics filled in class notes_Part_106 - 6.3 CONCISE...

This preview shows document pages 1 - 2. Sign up to view the full document.

View Full Document
Ask a homework question - tutors are online