Thermodynamics filled in class notes_Part_118

71121 mathematical model 711211 kinetics for the

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Unformatted text preview: rm. 7.1.1.2.1 Mathematical model 7.1.1.2.1.1 Kinetics For the reversible O − O2 reaction, let us only consider reaction 13 from Table 7.2 for which 13 : O2 + M ⇌ O + O + M. (7.100) For this system, we have N = 2 molecular species in L = 1 elements reacting in J = 1 reaction. Here a13 = 1.85 × 10 11 mole cm3 −1 (K )−0.5 , β13 = 0.5, E 13 = 95560 cal . mole (7.101) Units of cal are common in chemistry, but we need to convert to erg , which is achieved via E 13 = 95560 cal mole 107 erg J...
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