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keyfinalexam - CHM 2200C April 28, 2005 Final Exam Name...

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CHM 2200C April 28, 2005 Final Exam Name _________ KEY ___________________ (Please Print) The test consists of six pages. Print your name legibly on each page now. A seventh page contains approximate pK values for some acids. You can tear this page off and use as scratch paper. If something is not clear, raise your hand and ask! Points (4) 1. Draw the structure of each of the following alkanes (condensed, line, or combination): 2 pts each structure. 1 pt minor mistake. Page Points 1 _ 16 _ 2 _ 17 _ 3 _ 24 _ 4 _ 16 _ 5 _ 14 _ 6 _ 13 _ Total __ 100 _ (a) 1- sec -butyl-4-isopropylcyclohexane (b) 3,5-dibromo-4,4-diethyl-2-methoxynonane Br Br O (4) 2. In the structure at the right, identify the hybridization of the sigma bonds to each of the carbon atoms specified by a letter. 1 pt each A: _ sp2 ___ B. __ sp3 ____ C. _ sp2 ___ D. __ sp _____ H 3 C C H 3 C CH H 2 C C O C C CH CH 3 OH A B C D (4) 3. In the structure at the right, identify whether each of the specified carbon atoms is a primary, secondary, or tertiary carbon. 1 pt each A. __ primary_ __ B. __ tertiary ___ C. __ secondary _ D. __ tertiary ___ C H 3 C CH 3 A B C D H (4) 4. Draw four structural isomers of the compound C 5 H 10 . any 4, 1 pt each stereochemistry not needed cis or trans, not both cis or trans, not both
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CHM 2200C—Final Exam Page 2 Name______ KEY _____________________ (4) 5 Name the following compounds, including a cis or trans designation if necessary. 2 pts each. 1 pt for minor mistake. (a) Br (b) CH 3 CH 3 Name: cis-5-bromo-6-ethyl-2-methyl-3-nonene Name: _ cis-3,4-dimethylcyclopentene ____ (2) 6. Draw the structure of the major product of the following addition reaction: HCl Cl (3) 7. Name the following addition polymer, and draw the structure of the monomer which polymerizes to form it. 1 pt name, 2 pts structure CH CH 2 CH CH 2 CH CH 2 CH CH 2 CH Cl Cl Cl Cl Cl Polymer Name: __ polyvinyl chloride _____ Monomer Structure: Cl (8) 8. Draw the Saytzeff dehydration product and the oxidation product of the following alcohol.
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This note was uploaded on 11/27/2011 for the course BSC 5936 taught by Professor Staff during the Spring '08 term at FSU.

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keyfinalexam - CHM 2200C April 28, 2005 Final Exam Name...

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