problem_set8 - 2. Show that the standard deviation or...

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10.40 Thermodynamics Fall 2003 P r o b l e m S e t 8 1. Compute U/(RT) of a mole of diatomic ideal gas molecules treating the vibrational mode classically. Assume that the vibrational frequency is
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Unformatted text preview: 2. Show that the standard deviation or square root of the variance of the distribution of particle densities, , for a pure fluid varies as (< N >)-1/2 for a fixed volume system. For typical thermodynamic systems, what happens to the value of / <> at low densities and at the critical point? 3. Problem 10.11 in the text 4. Problem 10.12 in the text Be sure to state and justify all assumptions made. Modified: 12/21/2004...
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This note was uploaded on 11/27/2011 for the course CHEMICAL E 20.410j taught by Professor Rogerd.kamm during the Spring '03 term at MIT.

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