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Unformatted text preview: 3. Provide a mechanism for the following. No deuterium incorporation was observed in the absence of light. Show arrow pushing. CCl 3 CCl 3 h Cl + CCl 4 + O O Cl h 10 : 1 Ph Ph CH 3 ROD CD 3 h Br CCl 3 CCl 3 + + BrCCl 3 Br 1 : 10 4. Provide a mechanism for the following; show arrow pushing. 8. For the reactions presented in question 7, explain the difference in product distribution between the reactions employing CCl 4 and nitrosyl chloride CH 3 h CH 3 O HO O N BrCCl 3 . HO OH Hint: weak bond mixture of E- and Z-oximes pyridine N 1/1...
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This note was uploaded on 11/27/2011 for the course CHEMICAL E 20.410j taught by Professor Rogerd.kamm during the Spring '03 term at MIT.
- Spring '03