07_lec_7_2006 - 7 Massachusetts Institute of Technology...

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7 Massachusetts Institute of Technology Organic Chemistry 5.13 September 20, 2006 Prof. Timothy F. Jamison Notes for Lecture #7 Material Provided on Hour Exam 1 (Friday, September 29, 2006) The following 4 pages will be provided to you as reference material for the hour exam on Friday, September 29, exactly as they appear here. (Some of this information has been distributed in previous lecture handouts.)
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Infrared Spectra: Tables of Reference X-H Region Phenols and Alcohols Acids Amides and Amines C-H bonds 3700-3500 sharp or 3200-3600 broad(H-bonded) 2800-3600 very broad 3300-3500 ROH RCO 2 H RCONHR R 2 NH C C H C C H C C C C H O C C C C C C C RCHO sp Region Acetylenes Nitriles Ketenes Allenes C N Double Bond Region Alkenes Imines Nitro C N NO 2 1600-1670 weak unless conjugated 1600-1700 1350-1550(two bands) O O O O O O O O O O O O NR NR O 1710 1740 1780 1770 1730 1680 1715 1740 1690-1740 1650 6-membered and larger cyclic ketones 1720-1740 1700 1630-1700 1700-1725 1725-1755 1790-1815 Aldehydes Urethanes Amides Acids Esters Acid Chlorides
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07_lec_7_2006 - 7 Massachusetts Institute of Technology...

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