09_lec_9_2006 - Please see:

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9 Massachusetts Institute of Technology Organic Chemistry 5.13 September 27, 2006 Prof. Timothy F. Jamison Notes for Lecture #9 Organic Structure Determination The structures of the compounds corresponding to the spectra and data on the following pages are (fill in the blanks) : 8-A 8-F 8-B 8-G 8-C 8-H 8-D 8-E
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8-A Graphs removed due to copyright restrictions. Please see: http://www.aist.go.jp/RIODB/SDBS/cgi-bin/direct_frame_top.cgi?lang=eng
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8-B Graphs removed due to copyright restrictions. Please see: http://www.aist.go.jp/RIODB/SDBS/cgi-bin/direct_frame_top.cgi?lang=eng
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8-C Graphs removed due to copyright restrictions. Please see: http://www.aist.go.jp/RIODB/SDBS/cgi-bin/direct_frame_top.cgi?lang=eng
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8-D Graphs removed due to copyright restrictions. Please see: http://www.aist.go.jp/RIODB/SDBS/cgi-bin/direct_frame_top.cgi?lang=eng
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8-E Graphs removed due to copyright restrictions. Please see: http://www.aist.go.jp/RIODB/SDBS/cgi-bin/direct_frame_top.cgi?lang=eng
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8-F Graphs removed due to copyright restrictions.
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Unformatted text preview: Please see: http://www.aist.go.jp/RIODB/SDBS/cgi-bin/direct_frame_top.cgi?lang=eng 4000 3000 2000 2268 IR Spectrum (liquid film)-1 1600 1200 800 (cm ) 20 40 29 66 C 5 H 6 N 2 Mass Spectrum M + . = 94 (< 1%) 80 120 m/e 160 200 240 280 40 % of base peak 60 80 100 200 Proton Decoupled Solvent TMS 13 C NMR Spectrum (20.0 MHz, CDCl 3 Solution) 160 120 80 40 (ppm) TMS 1 H NMR Spectrum (100 MHz, CDCl 3 Solution) 10 (ppm) 9 8 7 6 5 4 3 2 1 Images by MIT OCW. 4000 3000 2000 IR Spectrum (liquid film) (cm-1 ) 1600 1200 800 20 40 66 78 C 6 H 7 N max 262 nm (log 10 3.6) UV Spectrum Solvent : Methanol Mass Spectrum M + . 93 80 120 m/e 160 200 240 280 40 % of base peak 60 80 100 Solvent 13 C NMR Spectrum (50.0 MHz, CDCl 3 Solution) (ppm) 200 160 120 80 40 TMS 1 H NMR Spectrum (200 MHz, CDCl 3 Solution) 10 8.6 8.4 Expansion 7.4 7.0 ppm (ppm) 9 8 7 6 5 4 3 2 1 Images by MIT OCW....
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09_lec_9_2006 - Please see:

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