jw_2 - Jeewoo Lim 2-1 2 : R e act io ns t o Kn ow 1 . Add i...

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Unformatted text preview: Jeewoo Lim 2-1 2 : R e act io ns t o Kn ow 1 . Add i t io n t o Alk e n e s- Alkyl hal i d e f o r m at io n HX H X X = B r , C l , o r I . H al oge n e nds up o n th e mo r e s ub st i t u t e d car bo n (M ark ov n i k ov Add i t io n ) .- Alc o h o l f o r m at io n: M ark ov n i k ov 1 . Hg(O Ac ) 2 OH (Ox y me rc u rat io n ) 2 . N a BH 4 , H OH-- Alc o h o l f o r m at io n: ant i-M ark ov n i k ov 1 . BH 3 H (H ydr obo rat io n ) 2 . H 2 O 2 , OH OH-- 1,2- Glyc o l f o r m at io n ( d i hydr ox ylat io n ) : syn add i t io n 1 . O s O 4 HO OH 2 . H 2 O, N a 2 SO 3 ( ant i add i t io n c ou ld be ach ieve d thr oug h: 1) epoxi d e f o r m at io n , f o ll owe d b y 2) epoxi d e r i n g ope n i n g . )- Alkan e f o r m at io n ( r e d u ct io n o f d oub l e bo nd ) H 2 , P d /C H H ( syn add i t io n: bo th H at om s add fr om th e sa me fac e o f th e alk e n e) o r H 2 /P t- B r omo( and chl o r o) e th e r f o r m at io n X 2 R O ( ant i add i t io n. X=B r o r C l ) R OH X 2 .....
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jw_2 - Jeewoo Lim 2-1 2 : R e act io ns t o Kn ow 1 . Add i...

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