ps6 - Massachusetts Institute of Technology Problem Set 6,...

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Massachusetts Institute of Technology 5.12, Spring 2005 Problem Set 6, Due 4pm April 7 1. Consider the following reaction. acetone CH 3 Br OH CH 3 OH Br a . If [CH 3 Br] is doubled, the rate of the reaction is: quartered halved same doubled quadrupled b. If [OH - ] is doubled, the rate of the reaction is: quartered halved same doubled quadrupled c. If both [CH 3 Br] and [OH - ] are doubled, the rate of the reaction is: quartered halved same doubled quadrupled 2. Consider the following reaction. H 2 O (CH 3 ) 3 CBr (CH 3 ) 3 COH HBr a. If [(CH 3 ) 3 CBr] is doubled, the rate of the reaction is: quartered halved same doubled quadrupled b. If [H 2 O] is doubled, the rate of the reaction is: quartered halved same doubled quadrupled c. If both [(CH 3 ) 3 CBr] and [H 2 O] are doubled, the rate of the reaction is: quartered halved same doubled quadrupled 1
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3. Draw the mechanism of the following reactions and the resulting products. Use curved arrows to indicate the direction of electron flow and show any reaction intermediates.
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ps6 - Massachusetts Institute of Technology Problem Set 6,...

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