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infoexam_01

# infoexam_01 - MIT OpenCourseWare http/ocw.mit.edu 5.62...

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MIT OpenCourseWare http://ocw.mit.edu 5.62 Physical Chemistry II Spring 2008 For information about citing these materials or our Terms of Use, visit: http://ocw.mit.edu/terms .

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Information for Hour Exam The exam will be closed book and closed notes, but you will be allowed one sheet of 8.5 × 11" paper (both sides) with your own notes, equations, and inspirational quotations. YOU MUST BRING A “SIMPLE” CALCULATOR!! MATERIAL COVERED: Lectures 1-12 Problem Sets 1-3 Combinatorics All thermodynamic quantities (U, H, A, G, S, µ, C V , C p , p) from Q. Multinomial trick and, for n i 1 , replace N! by N! n i ! i Q = q N provided that q N, equivalent to e –µ/kT = q/N 1 N! (+1 FD, no 1 B, –1 BE) ω (n,g) for BE, B, and FD FD B BE n i n i n i h 2 L 2 M 2 N 2 = ε L,M,N 8m a 2 + b 2 + c 2 = 2 π mkT 3/2 V V = abc (crucial approximation in deriving q trans ?) q trans h 2 ε → q Q thermodynamic quantities. Key is ln(q) permits all key contributions to be separated as additive factors. n i = 1 e ε i µ ( ) kT ± 1
Classical Mechanical formulation q Cl = h 3
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infoexam_01 - MIT OpenCourseWare http/ocw.mit.edu 5.62...

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