reactions - Por: Karinel Nieves Merced Orgnica 2004-05 Br2...

Info iconThis preview shows pages 1–4. Sign up to view the full content.

View Full Document Right Arrow Icon
1 Por: Karinel Nieves Merced Orgánica 2004-05 Br 2 h ν Br OTs NaCN DMSO CN Br CH 3 OH OCH 3 Br H 2 O NaOH Br +OH +ONa Br 1. LDA/THF/-78C 2. H 2 O, H (Saytzeff) (Hofmann) (Hofmann) Br H 2 O OH Br CH 3 OH OH H 2 SO 4 HBr H 2 O 2 Br H, H 2 O OH OCH 2 CH 3 1. Hg(OAc) 2 , CH 3 CH 2 OH 2. NaBH 4 , CH 3 OH 1. BH 4 :THF 2. H 2 O 2 , NaOH OH OH HBr Br HBr Br (Markovnikov) (anti-Markovnikov) H 2 Pt Br 2 CCl 4 Br Br Br 2 H 2 O Br mCPBA CH 2 Cl 2 O MMPP CH 3 OH O H 2 O O Br OH NaOH Br Br NaI OH H O OH O NaOCH 3 CH 3 OH OCH 3 HOCH 3 OH OCH 3 OsO 4 H 2 O 2 OH OH KMnO 4, frio H 2 O, NaOH OH OH 2. Me 2 S KMnO 4, H 2 O, NaOH 1. O 3 O O + O O + HO OH 2 H 2 SO 4
Background image of page 1

Info iconThis preview has intentionally blurred sections. Sign up to view the full version.

View Full DocumentRight Arrow Icon
2 Por: Karinel Nieves Merced Orgánica 2004-05 H NaNH 2 / NH 3 O 1. / HMPA 2. H 2 O, H OH O 1. / HMPA 2. H 2 O, H OH Br Br NaOH Br 2 , xs CCl 4 HBr Br Br Br Br Br Br H 2 , Pd, BaSO 4 quinolina, CH 3 OH (Lindlar) Na 0 / NH 3 H HgSO 4 , H 2 SO 4 H H Br H 2 O O H O 1. (Sia) 2 BH : THF 2. H 2 O 2 , NaOH HBr H 2 O 2 KMnO 4 , H 2 O warm O O 1. O 3 2. Me 2 S O O 1. KMnO 4 , KOH, H 2 O, 2. H, H 2 O HO OH O O HO OH Br Br Br Br KOH, 1. NaNH 2 , 2. H, H 2 O O 1. CH 3 CH 2 MgBr, Et 2 O 2. H 3 O + OH 1. CH 3 CH 2 MgBr, Et 2 O 2. H 3 O + O (Grignard) OH 1. CH 3 CH 2 MgBr, Et 2 O 2. H 3 O + Cl O OH Br Mg 0 , Et 2 O MgBr * Se protona con -OH, -NH, -SH o -C C-H * MgBr D D 2 O O 1. CH 3 CH 2 MgBr, Et 2 O 2. CH 3 Br, DMSO OCH 3 OH 1. NaOH 2. CH 3 Br, DMSO O 1. CH 3 CH 2 MgBr, Et 2 O 2. H 3 O + OH 1. CH 3 CH 2 MgBr, Et 2 O 2. H 3 O + O O CO 2 OH O CN 1. CH 3 CH 2 MgBr, Et 2 O 2. H 3 O + C O O O 1. CH 3 CH 2 MgBr, Et 2 O 2. H 3 O + O OH OH O OH O 1. CH 3 CH 2 Li 2. H 3 O + O Cl O 1. (CH 3 CH 2 CH 2 ) 2 CuLi 2. H 3 O + O (Gilman)
Background image of page 2
3 Por: Karinel Nieves Merced Orgánica 2004-05 Grupos Activantes (orto, para) -OH, -NH 2 , -OR, -NHCOCH 3 , -R, -Ph Grupos Desactivantes (orto, para) -F, -Br, -Cl, -I Grupos Desactivantes (meta) -COCH 3 , -SO 3 H, -CN, -NO 2 , -N + R 3 H O O O CH 3 OH, H 2 O NaBH 4 H OH O O H O O O 2. H 3 O + 1. LiAlH 4 , Et 2 O H OH
Background image of page 3

Info iconThis preview has intentionally blurred sections. Sign up to view the full version.

View Full DocumentRight Arrow Icon
Image of page 4
This is the end of the preview. Sign up to access the rest of the document.

This note was uploaded on 11/27/2011 for the course CHEM 6210 taught by Professor Wang during the Spring '11 term at University of New Orleans.

Page1 / 12

reactions - Por: Karinel Nieves Merced Orgnica 2004-05 Br2...

This preview shows document pages 1 - 4. Sign up to view the full document.

View Full Document Right Arrow Icon
Ask a homework question - tutors are online