ps2_1980

ps2_1980 - (c) Is the energy level diagram for Dk su...

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MIT OpenCourseWare http://ocw.mit.edu 5.80 Small-Molecule Spectroscopy and Dynamics Fall 2008 For information about citing these materials or our Terms of Use, visit: http://ocw.mit.edu/terms .
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MASSACHUSETTS INSTITUTE OF TECHNOLOGY Chemistry 5.76 Spring 1980 Problem Set #2 1. See Problem Set # 2, 1977, question # 1. 2. See Problem Set # 2, 1977, question # 2. 3. See Problem Set # 2, 1977, question # 3. 4. See Problem Set # 2, 1977, question # 4. 5. See Problem Set # 2, 1977, question # 5. 6. (a) See Problem Set # 2, 1977, question # 6(a). (b) See Problem Set # 2, 1977, question # 6(b).
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Unformatted text preview: (c) Is the energy level diagram for Dk su ciently complete that the electronic partition function q e = g i exp[ E i / kT ] , all states i may be calculated at 3000K? If one or more electronic terms are missing, what would be the fractional error in q e , assuming plausible term energies? Can you devise an experiment which samples q e ( T ) with accuracy su cient to locate a missing low-lying electronic term?...
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ps2_1980 - (c) Is the energy level diagram for Dk su...

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