ps3_1982

ps3_1982 - MIT OpenCourseWare http://ocw.mit.edu 5.80...

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Unformatted text preview: MIT OpenCourseWare http://ocw.mit.edu 5.80 Small-Molecule Spectroscopy and Dynamics Fall 2008 For information about citing these materials or our Terms of Use, visit: http://ocw.mit.edu/terms . MASSACHUSETTS INSTITUTE OF TECHNOLOGY Chemistry 5.76 Spring 1982 Problem Set #3 1. See Problem Set # 3, 1976, # 2. 2. See Problem Set # 3, 1976, # 5. 3. See Problem Set # 3, 1976, # 6. 4. See Problem Set # 3, 1976, # 7. 5. See Problem Set # 3, 1976, # 8. 6. The classical statement of the Franck-Condon principle is that, in an electronic transition, an electron jumps before the nuclei can alter their positions and momenta. In wave mechanics, position and momenta are not sharply defined for an energy eigenstate, yet we persist in drawing diagrams with vertical lines connecting turning points and using these diagrams to predict the strongest transitions. See J. Tellinghuisen, Phys. Rev. Lett. 34 , 1137 (1975) and Chem. Phys. Lett. 29 , 359 (1974)....
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ps3_1982 - MIT OpenCourseWare http://ocw.mit.edu 5.80...

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