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Unformatted text preview: What is the degeneracy of ψ mol for the above state with J = 6 instead of 5? 4. See Problem Set # 4, 1977, question # 6. 5. 16 O 12 C 32 S is a linear molecule. The bond lengths are r CO = 1 . 16Å r CS = 1 . 56Å and the observed fundamental vibrational frequencies are ν 1 = 858 . 9 cm − 1 stretch ν 2 = 520 . 4 cm − 1 bend ν 3 = 2062 . 2 cm − 1 stretch. (a) Obtain k CS , k CO , and k θ [ r CO r CS ] − 1 in dynes / cm. (b) What are the amplitudes for C-O and C-S stretch in ν 1 ? (c) What are the vibrational frequencies for 18 O 12 C 32 S?...
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- Spring '04
- RobertField
- Mole, MIT OpenCourseWare, Massachusetts Institute of Technology, Spectroscopy and Dynamics, ν1
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