Unit5_Kinetics - Chem 31L Fall 2011 R MacPhail/C Roy Unit 5...

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Chem 31L Fall 2011 R. MacPhail/C. Roy Unit 5: Chemical Kinetics Goals: To gain a fundamental understanding of, and develop chemical literacy regarding the principles and applications of chemical kinetics ; more specifically, to understand: (1) how the time- dependence and rates of chemical reactions can be characterized quantitatively, (2) how various factors influence the rate, and (3) how the observed chemical kinetics reflect the molecular processes in the underlying reaction mechanism Reading: Chapter 15 Suggested Questions & Problems: Chapter 15: o Expressing rates of reaction: #12, 13, 15 o Determination of rate laws—Initial Rates Method: #17, 21, 23, 25 o Determination of rate laws—Integrated Rate Laws: #29, 31, 33, 35, 37, 43 o Evaluation of Reaction Mechanisms: #53, 55, 57, 59 o Steady-state Approximations: #61, 62, 63, 101 o Temperature Dependence of Rate Constants: #67, 69, 71, 73, 75, 99 o Catalysis: #81, 82, 84, 97 o Challenge Problems: #103 Relevant Background Concepts: Chemical Equations, Balancing, and Stoichiometric Calculations, Sections 3.6–3.8 The Composition of Solutions, Section 4.3
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