10052011assignment

10052011assignment - Each atom now has three degrees of...

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Carry out a full vibrational analysis of the following three molecules a) PtCl 4 -2 Square planar b)CH 4 Tetrahedral c)MoL 6 Octahedron First carry out an analysis for the stretching vibrations (each bond is a vector and find the characters of the reducible representation). Then carry out an analysis of all motions.
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Unformatted text preview: Each atom now has three degrees of freedom (place a small cartesion coordinate system on each atom and apply the symmetry operations). Take out the rotational and rotational degrees of freedom. Then decide whether the vibration is Infrared or Raman active. Due 7/12/2011...
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