MultielectronAtomEPSolnF2011

MultielectronAtomEPSolnF2011 - M E 501 Multielectron Atom...

Info iconThis preview shows pages 1–3. Sign up to view the full content.

View Full Document Right Arrow Icon
ME 501 Multielectron Atom Example Problem From N. M. Laurendeau, Statistical Thermodynamics 3.12 The following exercises are concerned with determining the degeneracy of various electronic energy levels. a. Two closely-spaced, excited energy levels of atomic nitrogen have the configu- ration 1s22s 2 2p 2 3s. What are the values of Land S for each energy level? For both levels, determine the multiplicity, the term symbol and degeneracy of each member of the multiplet, and the cumulative degeneracy (neglecting multiplet splitting). b. Two low-lying, but closely-spaced, excited energy levels of calcium have the configuration ls22s 2 2p 6 3s 2 3p 6 4s3d. What are the values of L and S for each of these energy levels? For both levels, determine the multiplicity, the term symbol and degeneracy of each member of the multiplet, and the cumulative degeneracy. ?p )0, ( J2 '"L -- I [[3 -- 0 - 1- ~ - / S5 -::::- 1j2- - 2-Z 51 2- ~~ 35 :3 6 1 ~ 1- -- L 2) I J 0 ""2- J ~ p Z 8 .f- I - Z;Lf D S ~,s ---- ({?/VV\)i. '"2-0 4-0 '7P '-+p Lf t ::3! ) I J / J
Background image of page 1

Info iconThis preview has intentionally blurred sections. Sign up to view the full version.

View Full DocumentRight Arrow Icon
- - (\ ~ 0 5 (2 5 ~ Co ? t:J 3(2 J -= If -==-2J-t{ ~ ~- '-tQ J 6 <-' 4 0 7 (2 S~ g L)!Z- £-I j~2 /1 ? 4
Background image of page 2
Image of page 3
This is the end of the preview. Sign up to access the rest of the document.

Page1 / 6

MultielectronAtomEPSolnF2011 - M E 501 Multielectron Atom...

This preview shows document pages 1 - 3. Sign up to view the full document.

View Full Document Right Arrow Icon
Ask a homework question - tutors are online