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PKMCONCEPT_9 - • Understand the Relationship between ∆...

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Third Law of Thermo Definition of Gibss (G) and Helmholtz (A) Free Energies: G = H - TS A = U - TS Differentials dU, dH, dA, dG and dS dU = -PdV + TdS dH = VdP + TdS dA = -PdV _SdT dG = VdP -SdT dS = (Cp/T) dT - α VdP or dS = (Cv/T) dT + ( α / κ T ) dV The second law of thermo expressed with G for systems at constant P & T. The second law of thermo expressed with A for systems at constant V & T.
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Unformatted text preview: • Understand the Relationship between ∆ A and the maximum work done under isothermal conditions and ∆ G and the maximum non-expansion work done under isothermal and isobaric conditions. • Maxwell Relations: How to derive them, how to remember them and to recognize them. How to derive π T and ( ∂ H/ ∂ P) T using Maxwell relations. Weeks #9 and #10...
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