PKMCONCEPT_9 - Understand the Relationship between A and...

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Third Law of Thermo Definition of Gibss (G) and Helmholtz (A) Free Energies: G = H - TS A = U - TS Differentials dU, dH, dA, dG and dS dU = -PdV + TdS dH = VdP + TdS dA = -PdV _SdT dG = VdP -SdT dS = (Cp/T) dT - α VdP or dS = (Cv/T) dT + ( α / κ T ) dV The second law of thermo expressed with The second law of thermo expressed with
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Unformatted text preview: Understand the Relationship between A and the maximum work done under isothermal conditions and G and the maximum non-expansion work done under isothermal and isobaric conditions. Maxwell Relations: How to derive them, how to remember them and to recognize them. How to derive T and ( H/ P) T using Maxwell relations. Weeks #9 and #10...
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This note was uploaded on 12/24/2011 for the course CHEM 3615 taught by Professor Aresker during the Fall '07 term at Virginia Tech.

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