Unformatted text preview: intermediates O Write reaction mechanism in terms of elementary reaction steps O Write the rate law for intermediates dilrternedia tel _ dt Apply stead-state approximation d[Internredia te] _ O dt Use O and I to solve for [Intermediate]: [Intermediate] : ... Write rate law for reactant, including dependence on [Intermediate] dfReactart] dt Substitute expression for [Intermediate] into rate law for reactant Arrhenius Equation Plot of ln(fr) versus l/T gives a straight line. Equation for this relationship: frequency factor ,-- Activation Energ;r t_L A E",r1) ktk:WA)-,n,[rJ 'r Universal Gas Constant (8.3145 JKimolr) k = 4s-E"lnr Alternatively we can write this as:...
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- Fall '10
- Reaction, Chemical reaction, Svante Arrhenius