IMG_0001_NEW_0037 - CH:OH Cl-HO CH:F-CHTOH F-whv L0 i wwr...

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2. what if the electrophilic carbon atom is chiral? (e.g. (2R)-2-bromobutane) *) C)\ rq,^>)q s flb I 4 J uO,-'.-.i.--- L" lrn cl4/]1 1K I 9-M . -) 37 P"ol'*ue 7 3. How well does the leaving group bear'the negative charge? ability) relative rate ofreaction "' sNL RuN pfqrr{ "4h intflr9'o11 -f Are,.ohmiS+,y Ls) E.tA. _r rR) pfuuL !-l+ r"J tC\ r) Ho-ci ("H ctl,At @ w0 f-'yWf ry @ HO- + CH:I --+ CH3OH + I HO- + CH:Br -CH:OH+Br- HO- + CH;CI -*
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Unformatted text preview: CH:OH + Cl-HO- + CH:F -CHTOH+F-whv? L0 i+ wwr[, r*1t "19'bV -uI!'^ f-1 _?-) +g (AKA leaving group e- t' l- t-^+ LHo,* c '.-." D. ) t'-. hh 30,000 10,000 200 1 ), ts. Wol!( Lot't '*V le'ta l*t 1* ^/"'"tL o qt E 'd ho ( wrzln,^*o -04^,1 t,a.^ fW I 4"1* *;r)) PVA f is ,,^A t*AW ar U'ltl;q ya-ra'^4 I *7 h 75, +1v"1' (""tt/ fW ? Wor lt ry %rf HT HW fu4 HT X"*vr qH'rt+ ,F + t,riyX FvP 7ry*r5 X=a...
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This note was uploaded on 12/27/2011 for the course CHEM 281 taught by Professor Williams during the Fall '11 term at Simon Fraser.

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