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Quiz 3 - 1 Predict the products of the following...

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Chem 41b Quiz 3 Grubbs/Stoltz, Winter 2011 January 28, 2011 DUE: January 31, 2011 at 9 am You have 30 min to take this quiz. It is closed note, closed book, and no collaboration is allowed. Please do not discuss the quiz with anyone until you receive it back graded. Place a box around your answers. There is no partial credit. Name______________________________________
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Chem 41b Quiz 3 Grubbs/Stoltz, Winter 2011 January 28, 2011 DUE: January 31, 2011 at 9 am You have 30 min to take this quiz. It is closed note, closed book, and no collaboration is allowed. Please do not discuss the quiz with anyone until you receive it back graded. Place a box around your answers. There is no partial credit.
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Unformatted text preview: 1. Predict the products of the following reactions (10 points) A. Hg(OAc) 2 (catalytic amount) H 2 O, MeOH O O 2 major products B. 1. 2. NaOH, H 2 O 2 H B H O 2. Provide a synthesis of ONE the following compounds starting from compounds of 3 carbons or fewer(10 points-TA’s will give partial credit ) O OCH 3 A B 1. LDA, EtMgBr, or NaNH 2 2. w/H 2 O work-up O HO (or direct quench with Et–X) 1. base, Et–X 2. Na, NH 3 (liq) A OH 1. base, Me–X 2. LDA, EtMgBr, or NaNH 2 3. Et–X OCH 3 Lindlar cat H 2 B Bonus (5 points-TA’s will give partial credit) Draw a mechanism for the reaction of borane 1 with H 2 O 2 and NaOH to produce 3-hexanone. B O O 1...
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Quiz 3 - 1 Predict the products of the following...

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