answer key for final practive - reactive toward EAS: OMe...

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1) Provide a curved arrow mechanism for the following transformation: NAM NAM E CHEM 236 Review Material AD5 Me OH D Me O DCl 3) Predict the MAJOR product (only) for the following reactions : NO 2 FeBr 3 Br 2 , heat FeBr 3 Br 2 , heat OMe 1. AlCl 3 , 2. H 2 O Cl O HO MnO 2 Me FeBr 3 Br 2 , heat MeO Me OH D Cl Me OH D H Me OH D D Me O H Cl - D Me O Br MeO O NO 2 Br O Me MeO Br
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4. Provide a synthesis : (Hint: use another carbon containing material that contains five carbons and one degree of unsaturation) 2) a. Provide two examples of structures that ARE NOT BENZENE OR SUBSTITUTED BENZENE that exhibit aromaticity: b. Draw three resonance structures of anisole that explain why it is so
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Unformatted text preview: reactive toward EAS: OMe anisole OMe OMe OH Me Me 5. Describe the relationship between the following compounds as diastereomers , enantiomers , or same compound : O Cl H Br H H H OH CH 3 H H CH 3 HO Cl Cl OH HO OH OH OH O OH HO OH OH OH H 3 C Br Cl H D H D H MeO OMe S N Etc. OMe OMe OMe OMe OMe OMe O OMe OH 1. AlCl 3 , 2. H 2 O Cl m-CPBA H + Enantiomers Enantiomers Same Compound Same Compound Diastereomers...
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This note was uploaded on 12/30/2011 for the course CHEM 236 taught by Professor Baranger during the Spring '08 term at University of Illinois at Urbana–Champaign.

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answer key for final practive - reactive toward EAS: OMe...

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