Lecture8CHM233(10)final

Lecture8CHM233(10)final - ! Organic Chemistry, Third...

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Unformatted text preview: ! Organic Chemistry, Third Edition Janice Gorzynski Smith University of Hawai’i Chapter 4 Alkanes # Give the IUPAC name for the following structure A- 2-methyl-3-ethylheptane B- 2-methyl-3-propylheptane C- 4-isopropyloctane D- 4-(1-methylethyl)octane E- both C and D $%&'())* + ,- ()-. /,01&2 3. 4 5.')6 78 %.//8%& (9-58/2 :.58;8/< =.)).5,90 &18 7..> ?.@89%)(&'/8 A ,- ( -'B%,89& (9-58/ Give the IUPAC name for the following structure A) 5- sec-butyl-2,4-dimethylnonane B) 6- sec-butyl-2,4-dimethyldecane C) 6- sec-butyl-3,5-dimethyldecane D) 6-isobutyl-3,5-dimethyldecane E) 4-butyl-3,5,7-trimethylnonane ! C Figure 4.6 Newman Projections - Ethane D • Torsional strain is an increase in energy caused by eclipsing interactions. Figure 4.8 Torsional Energy of Ethane E Butane, Anti and Gauche Conformations F • Steric strain is an increase in energy resulting when non-bonded atoms are forced too close to one another. Steric Strain G Conformation and Energy of Butane Figure 4.10 H Barrier to Rotation !I Zigzag Skeletal Structures !!!...
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This note was uploaded on 01/03/2012 for the course CHEM 233 taught by Professor Anamoore during the Fall '10 term at ASU.

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Lecture8CHM233(10)final - ! Organic Chemistry, Third...

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