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Final_B - A Nnmenclature(12 ms 4 pts each Please provide an...

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Unformatted text preview: A. Nnmenclature (12 ms, 4 pts each) Please provide an acceptable name for each of the following campounds. Be sure to indicate the STEREOCEEWSTRY Where: appropriate. 2) 0 \/H \ . ch - v j" \ HgN f ._ _ m___.__r_ 3) B. Reactions: Total 2 42 poifits, 7' points each Please profide the major prodluct, or necessary reagents. or starting material in the answer box. Be sure your drawing Intimates stereochemistry if appficable. I '" "'" ‘" ‘f {3 1.05595“ ’ a CH3 “W " 2. harem) *Hnso EH 0 a I A 3 CH: 7: d 4 2 $ 4 {1 N _ NEgHgéN =/ 2 Q ... l 1. H531 ' 2. L R ' '3‘.‘c' F308;“? "’ CHgo CCfiHn r r I -.—u..__....____ _ 1 "—‘-'—"——-—--—+ 3‘ Mngs‘her 4 C} - u C53 -C—i"§ 5. H30“ 1 2. BrEICHgCIC‘gI—I I“? 6 2H0 cu- ”! H9 [ [ .500 C1} 1 [j 0 ll 4- CHJCHZCHZCHZ-C-Né-Ea ;n 1. Br lNaOHEHQO 2.0 w' {XS} - 92 3H2 3. eat f Foo {.33 C] J'H-uv C. Mechanism: (1? Pts) Provide a ciear mechanism for the reaction shown be!ow. Use curved arrow notation to indicate"oiectron flow". Show all intermediates and all formal charges. If there is more than one resonance structure, you muot Show the "best" {La Iowesi energy) structure. a i3 Q 1) NaOEt 2.1440“? 0 UHgl 4- ..._. .,_._.,_.__ a. _" 9 E20 ' ~ EtOH A 2 HQUR‘S {FE LfBFaAFi‘y’ :_;‘; i=5 C‘h‘L'r’ I ’ oo (“:3 D. Synthesis: 1? points Outline an efficient synthesis for the molecule: shown below using any of the following reagenis: fleshed; aflcene, andfor alkynes of (we carbons or less, benzene, and any inorganic reagents, any oxidizing or reducing agents and any peroxy acid. F; 00 (5) %C 58.3 ‘ . .. .. ass: I. “3......f. 2.. .2 mflahicfizfi x 1.0 PPHO.5 1.5 ' i 4.0 Frntun MI 1; ‘1'. .3 L 29 PPM 181215155, 140 126 100 so 50 4a I260 Carina 13 NMFI E00 ...
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