Final_C - A Nomenclature Totai 12 points 4 points each Give...

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Unformatted text preview: A. Nomenclature: Totai .-.-. 12 points. 4 points each Give an accep1able name for each of the compounds below. /'\ 2. CHECHE {EHS ‘EHE \ N—CH-CHz—CH—CHa / 1436112 F 0! I D. Synthesis: (1.7 pte) Synthesize the molecuie betow using an};r of the following reagents: benzene, cyclohexane, afcohels, a1kanes: aikenes, andfor alkynes of two carbons or less, any inorganic reagents, any oxidizing Gr reducing agents, and any peroxyacide. . O I “ C. Mechanism: {1? pie) Provide clear mechanisms for the follewing reaction. Use curved arrow noZation to indicate“eiectron flow". Show all intermediates and all formal charges. Efthere is more than one resonance structure! you must Show the "best" (Le. lowest energy} structure. ijo _ + 0W0 _rjlaOEt \flo 52cm \.__./ ‘b 1. KMnOflOI—I'Meat 2. HP w 3. 50012 4. 4. (CH3)QCULi 5. LDA i 6. CHQCHZI FII G O i! 15 d "“ 6. HECICH—CEN + CH3OCCH2COCH3 "NaOfH" 2.H30 {st’I-ieat :1 Q ____ / \ CH2NH2 ...___.._.._. -.__._.___.. B. Reactions: Total = 40 points, 8 points each Piease provide ihe magor product m necessary reagents in the answer box. Be sure your drawing indicates stereochemisw if applicable. Fania! credit is aWardcd only when intemediate pmducts are "awn beaow the reaction- "7-w— 1. N32Cf207m2804fl'120 1 . CH CH 2 2. SOCI2 a. LEAiH{OtBu)3 «(m-ng i : Aggomgon—Ieal O I] 0—0053 1 NH3 {Heat 1 3. _.._.4( N .W ... P \ 2. BrngaOHfl—igo 3 CH3? (x5) 4 ...
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This note was uploaded on 01/05/2012 for the course CHEM 3321 taught by Professor Bean during the Spring '11 term at American Jewish University.

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Final_C - A Nomenclature Totai 12 points 4 points each Give...

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