Final_C_Key - A‘ Nomenclature: Total = ‘2 points. 4...

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Unformatted text preview: A‘ Nomenclature: Total = ‘2 points. 4 points each Give an accepiable name for each of the compounds below. 3. Reactions; Total = 40 points, 8 points each Please provide the major product or necessary reagents in the answer box. Be sure yo ur drawing indicates stereochemistry if applicable. Partial credit is awarded only when intermediate products are " wm beiiow the reaction. 1. N32CI‘2073HZSO4JHQO ‘- / . G '- \- 3. LiAiH{OtBu)3 (3A E :5 a 4‘ (Qt-“:1” " A Q,C\ (.l I“ ! 3 V ' I h... - AK > 8 fi fr.) 1 l \\ v I J. H mu?) fig; sea, I 2 :- _H I ____ 1 J h— I-E'H‘ZA ST fflKNQL/HCI /\Br 1 m" ‘i - G WUL 3"}; f? I ./ Z 3 E 4 152‘ [a 1.4;, ‘a H) L @1’ A /\I$ll *— e ’5” c—QCH3 4 r / z. NH3 ; Heat 3' . __.. _.__ 1. > \ 2. BrgiNaOHIHQO ’" \ 3. CH3! (x5) f ff-x 4. AQQOMROMSEH it ks ' L; j 1 ___ . i 1. KMnOgJ OH'IHeat ' 2.H+ O 1 w / I 3.50012 1: 4. 4_(CH3)QCUL] w c‘ \\ l JS_LDA $5 v\ ' 6.0HQCHQI ' 5,1- ' \ I \i :2: ®/\Dh “3,9 “\ SE. 5 a bag.) ...J_._> “DH/.3 C. Mechanism: (17' pts) Provide clear mechanisms for the fotlowing reaction. Use curved arrow notation to indicate“e{ectron flow". Show all intermediates and all formal charges. Efihere is more than one resonance structure! you must Show the “besi” (Le. lowest energy} structure. D. Synthesis: (1‘? pts) Synthesiza the moEecuie below using any of the foilowing reagents: benzene, cyclohexane. alcohois, aikanes, alkenes, andfor alkynes of two carbons or less, any inorganic reagents, any oxidizing or reducing agents, and any peroxyacids. F' 0 I \ /— h-J 31% r o I rim: il—‘l O ...
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This note was uploaded on 01/05/2012 for the course CHEM 3321 taught by Professor Bean during the Spring '11 term at American Jewish University.

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Final_C_Key - A‘ Nomenclature: Total = ‘2 points. 4...

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