Final_F_key - A. Nomenclature: ( 4 points each 101a! = 12...

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Unformatted text preview: A. Nomenclature: ( 4 points each 101a! = 12 points) Please provide an acceptabte name for each of the wilowing compounds. ‘ o I! 1. QCHQ-NHCl-bCHg-C—OCHECHG f—g -* Q‘H’Wfl ' 3 “baggy? Gumamc: Froloanoaj I @553) '3 «a wmeh9*3“mé7%j/ 412%emmt __ __ »____.i 3. N“d fit-my -* 3* 1/1/1174.ng fxoflflmagfhfi V NV " /U' A; '- msé 4-: M avid-u awake {3 “may m p-L f - “ flmaf 5W , i E] 3. Reactions: {40 points, 8 pas. each) Please provide the reagents. or major organic product(s) in the answer boxes. Partial credit is awarded only when immediate products are shown below the reaeuon. i 1) NaOEthtOH I j? I E 2) NB: : i 3) H30+f1809C I [ i_~_____J 0 ’2’“) . . O 3. Oi 1} NH3 (large excess) 2) CH3I (excess) W J m...) ‘ ~ . . .4 I Mr: ' a $wag£5 HQ€WMV- _ U1 1) Hwog, Hgso4 2) Fe, HCI 3} NaOH 4) NaNOg HCI 5) CuCN a) LEAH-14 7) H20 Meek; iii-5’91. ~f7f3v1‘... image oHv-j— .m fwdzeje, %1{QQ_ hxmbe/‘r own! man. bé‘v‘fl ’5 ;\- i'm+‘p’“i=3 "rr'm‘t. l? . a S MP3, MW {*5 N»: a 5" Provide a; rggsonoblg mechanism for the reaction below. Use curved arrows to indicate “electron flow." Show 1331” mtermedlaTes and forms} charges. If there is more than one resonance contributor, you must at: show 9 "best" i.e.. Iowast en Ir . . . '- ( . ergy)s ucture 5+epq‘ Fatme pay C. Mechanism: 17 points 6* Nu. . ‘s .1“ €55. . a n 1‘ - 4g Gt.“+aVV‘€. 3 a“ _____ L yfi‘og. (5:: 6/34: $ P 3' .,____._.. H g 1. CHSCHQO‘ Na+rCH30H20I-Irl-IEAT 1 6 h C‘ ‘3 a? E? _ - _ H _ 2 O 2. {ms-cc 2.0-14 in CH30H20 Na+JCHgCH20H 3 o 5 3 ’H , . 3 Hafl" *- r I H it w "(NH W0 3"") 9 if c. . 6/0 Cir-gagfim mam Gaom— s fire-4 4° “We J PraobuCT AT“ ALL COST. D. Synthesis (17 points} Synthesize the compound beiow using any of the following reagents: alkanesfi alkenes, alkynes or alcoh 013 of two carbons or less, benzene, any oxidizing or reducing agents, and any inorganic reagents. 0 E. Spectroscopy: 10 Points A compound with the formula C9H13N exhibits the IR, 1H NMR. and protonrdecoupled 13 C NMR shown on the knowing page. Please. identify this compound and dmw the structure in the box provided beLow. ‘d TRHNEI‘III “NEE r1-‘—,-'§-. Ema capi Mar-q fl is Winn an plum —I" 1 “mm-w“ ~— nag! .— 113.7 l—-r . m -— no.1 integral values "“' "" 33.6 *"' 2].? 3H WNW ...
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This note was uploaded on 01/05/2012 for the course CHEM 3321 taught by Professor Bean during the Spring '11 term at American Jewish University.

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Final_F_key - A. Nomenclature: ( 4 points each 101a! = 12...

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