Final_G - A” Nomenclature: (15 minis; 5 points each}...

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Unformatted text preview: A” Nomenclature: (15 minis; 5 points each} Pisasa pm'vi-dc an acceptabie‘namarfm each tsfi-h-e-ifoumring campounds. .B.er:.s_t¥re.=ae now-siereachemiswy where appmpria‘ce. j . :fo 3. l l w; NH ‘I/k'Lfi M .5 f .r tum-J B; Reacfim52'TGtaY-m '43 point's.__ B paints each Pleasefpimvide the main: praduc’iin. th‘e-‘aniswer-Zboxfsr FIVE; of the. reactia'ns. Write-“3.3m!”- in theabox of themeactian yam-change: :tqm‘nit. Be sane-yourd'rawinjgs indicate. stereochem-istry iffiapjjlicabi'e. Partial {tréedit i’s award at: on‘ty when intermediate products arasmw-n bebw “the reaction. Br . . *1. HNOafi-iz‘S'O WW 2. H2 Pt 3. ‘4. m Cad/V -* 1 Heat 2-.ems-MagWaggon a.» 1 . 2. teams / 3 a. mama—130912;: eq‘) W 4. Na‘CN IH‘” J: mar-ri- 4} v/VG 1 ‘M-a‘OEU E{OH/h a _ w i ‘ ‘aZ-(Q—PmC{C'HS)2 ‘ . 3 r . .. i '0 1.. (OBSOHQQNH zw 2cmfi&mmmm% :32 E30? Wm“mm”f "I. CHSOHJ’l—W g a 2 NaECTQO'y '1’ H2804 ! 3. NH3 fheat .4. 53:72! NaOH 17-HQQ me C. Mechanism: 15 points PEeaae provide a clear mechanism for the reaction beiow. Use curved arrow flotafion toi'indicate "eiec’tmn flaw." Show all intermediates amd a1! ic‘rmal charges. if there is more‘rthanene resonance-structure; you‘must Show the “best” (513., lowest energy) structura O ‘0 O no N OEthtDE VKOCHa- “E” , W1 W1; D; Synthesis]: {Emma} ’Synthesfze thacompound below us£ng any of thefailowmg reagents: benzene and afkanesi ‘aikenes. .alkynesnr- alc'crh'oispflh'wa carbana--=or--ies&9an¥ QXidfizing or reducing agents: anyperpxyagids, and-any inorganic reagema Please note: “A starting material 111 ayinot contain :11 are than on-e-funcilonai group?- 0 . '. 9 A , ; i- : E ;-1~'_ J. 3 .I L I‘ ELS-p EmEDSC-Dpyi £1 SPoims A compeufld with-tilt:.fam1u1a-C4TE—19ND; axhibiusmem, 1H andgmtanrdagogpled 13::‘NMR 512mm :91;- the‘ following page. Phase; idamify this compoundfand draw- i‘haastmcmre in‘the box-previded beltjw. \ ' .3. ' 3.5 Prahnfi'flfifi WWW-11- , . ( iDEs Earhart £3 33414»? E “j E § :1: §.._____1 Sam-ts Question: 1,0 point-s Below are the IR, 1H NMR, and praiomfieccupied 13C: NMR- spectra Ufa compound ofunknown formal-a,The-Simmera?!1.3 ppm in me 1-H: NMR specn‘um'isflgOemh-angeabie. Prapose a gsiructure for this compound. Only answers En‘the be}: wii! be graded, ' H z “rmsmném _ .+#_..4 an”; Car'mr; !? NM}: ...
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Final_G - A” Nomenclature: (15 minis; 5 points each}...

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