Final_G_key - i :53 Kg" Please provide an...

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Unformatted text preview: i :53 Kg" Please provide an asceptabfle"name?er each ffif thegioi'icwing :compauncfs; *B‘esurei-a'o- note staree'chemistry where-appmpri'ata I 5) ' L'H«ompen+93\)’3' mmilum‘. nowmqoaérfi' A. Nomenciaturez (T5 points, 5 paints each) E” H’ ‘ NHcHE M 93 ?’Fymmo’5w (WI/{l vivhuidW-Ll “Ml?” "'ng f0 3 WWW I l g r z 3 g mm“! ‘7.-." B. “Esacfionsz: Total 2: 40 points; 8 points each Please provide the mam pmduct‘in the. answer b5): for FNE-o‘i ihereaetio‘ns. Wriie "emit" in the box of the reaction you choose to omit; Be au‘reyour drawings indicate stereochemistiy if applicabie. Partial-creditisawarded only when. infermediate pmducts weshownbelow the reaction. Br ' 2. H2 :91- m - m _ l x .. _ x a”. NaNOg-f H.er I. ‘7 4. W m 4/9 ‘ Q 1-. -Hr§03fi~él-28'Gg 1;. He at :2..'CM3NH2 maBHSCN )r-(lfla 0: 21:03am .- ' I 3. HOCchHEOku eq)‘ I H“ 3' a» 4.. NaCN 1w EH3 “A '0 . fl . _. I _. w ... . -. «'{uH36H-3)2N_H 4 H _ Lg) E‘CH3-—'C~GH=CHCH3 ‘W _ awoke; / / \ - WWW Mr “3. CH3©HXH+ --- 2. wager/£07 ragga; 6' 3mg meat- ') '4. ..r;3.r:g I! NaOH f H30 ' % C. MeCh-aniém: 1'5 poi-nits Plaa‘se providea dear mechanism-far the reaction -'be£o.w.. :Usg curved .-arrow- nfoiafian tofindicaie" “9195:5793 fiaWfliS‘nuw- an; intermedjiaies and all fp-rm-ai (:ih-agges, If there--:s.m0rethan .oh-gzr'esofiance-Structure, you must. Show The "beast":- {i,e;_, itcwes’; enargy.) .jstructgu re, UL. S}fith_e_s,is_: (195; points). Synthesize thecampwtwdbaiowusing anny the following reagentsrbenzena and aikane's, amen-ear aikyn es o'r washers-of three car-bonsr-or-iessgnany oxidizing” or reducing agents, anyparoxyac‘fds, aria any morgam‘c reagents. Piease note: A starting material may not contain morethan one functionai groups 0 4' ” m H20?“ “06+ m , O a If "@4{- + A H‘ \ . GD . N ‘ Cum 0 430615 . .. a . met?) 0 35mm Heal M12. a-—- i6, 2» “.1 a 'E-S‘pectmscopy: ES'PGim-s A compound with the‘iorm'uia-C4HQNG-ExhibitsIke-IR 1-H NMR, andpmtonadeceyyled 13C. NMRshofi-u-QI; the. foiiowing page. FIWC identifythis compound andsdmwfhe stmctum in the mmvi‘defi- balm»: 'u' 13.5" ' firm ts}: {GHQ m” '33" “"56 ' ' 3w" ' 72::st {iv Carma 1-3 Hm E Banw Question: 1D¢3¢ims Beiaw are the IR, 1'H NMR, and proton-decoupled 130 NMR‘ specira of a compound of'unknown formula The singIet-at 1.3 ppm in "the 11H NMF: spectrum is. Dgfi'axchangeafibifi Frag-pose a ._st'ru<:ture-far thismmpaund. Qniy answers inth box will be graded. ' ' ' 2- Twatmfmcs - U A. ‘ . " .w . F ifif.‘ 131? ‘t {91‘ 113 1139 3-5! Sf} 7C 513 55 AL‘ W.” E Cam» 1: mgr .L I . ...
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This note was uploaded on 01/05/2012 for the course CHEM 3321 taught by Professor Bean during the Spring '11 term at American Jewish University.

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Final_G_key - i :53 Kg&amp;quot; Please provide an...

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