Split_00006 - 9.11 a. bg bg n C 4 H10 g i C 4 H10 g Basis:...

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9- 6 9.11 a. b. c. d. ni −→ CH g 41 0 0 bg Basis : 1 mol feed gas 0.930 mol n-C 4 H 10 (n n- C4H10 ) out 0.050 mol i-C 4 H 10 ( n i-C4H10 ) out 0.020 mol HCl 0.020 mol HCl 149 ° C Q(kJ/mol) 149 ° C (n mol (n mol n-CH H out i-CH H out 0 0 ). ( . 4 0 0 ) . ) . . .400 .420 =− = =+×= 0 930 1 0 0 560 0 050 0 930 0 0 ξ ν mol H 10 H 10 10 H = = = () 0.560 0.930 n-C 4 n-C 4 out in n-C 4 nn 1 0 370 . ΔΔ Δ Δ ±± ± ± .. . HH H H in r o f o CH f o Table B.1 r o 0 0 kJ mol kJ mol = = −− ej 134 5 124 7 9 8 References : ° CH g a t 25C 0 0 , substance (mol) kJ mol (mol) kJ mol 1 in in out out 0 1 1 0 2 nHn H nH H iH ± . ± . ± 0600 0400 ± . HC d T p 1 Table B.2 kJ mol kJ mol = L N M M O Q P P = B z 25 149 14 29 ± . d T p 2 Table B.2 kJ mol kJ mol = L N M M O Q P P = B z 25 149 1414
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