chm 2120 assignment 3

chm 2120 assignment 3 - CHM-2120/2009 Assignment 3 T.Durst...

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CHM-2120/2009 Assignment 3 T.Durst This assignment deals with radical catalyzed addition to alkenes, polymerization 1,3-dienes, allylic systems such as allylic radicals and allylic carbocations. NOTE. Nomenclature questions will account for between 5-8 % of the Midterm exam. I am aware that you studied alkene nomenclature in CHM1123 therefore I did not repeat this in the course. 1. Name, or supply a structure to each of the following . a) E-3-bromohex-2ene; b) trans-2-methoxycyclohexan-1ol; c) 3,3- dimethylcyclopentene; d) Z-3-methylpent-2-en-1-ol; e) 2-cyclobutyl-pentan-2-ol; OH f) g) H 3 C OH h) H 2 C CH 3 H H H i) HO CH 3 CH 3 CH 3 OH j) H 3 C k) 2-hexyne; l) hept-1-en-6-yne; m) 1-ethynylcycpentanol. 2. Give the structure of the polymer that is obtained by polymerization of H 2 C CH 3 CH 3 a) b) CH 2 =CH-CO 2 CH 3 3. Indicate the weak bonds, if any , in each of the following molecules. O
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chm 2120 assignment 3 - CHM-2120/2009 Assignment 3 T.Durst...

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